Changes in the Composition of Polyaromatic Hydrocarbons of Siberian Oil Shales in the Modeling of Thermal Processes

IF 0.9 4区 工程技术 Q4 CHEMISTRY, MULTIDISCIPLINARY
I. S. Korol’, N. A. Mukhortina, D. I. Chuikina, N. A. Krasnoyarova
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Abstract

Thus article presents the results of studies of polyaromatic hydrocarbons (PAHs) in oil shales of the Barzas (Barzassite) and Budagovo (Sapropelite) deposits and their ash residues obtained upon thermal destruction at T = 300, 500, and 750°C with free access of oxygen. A set of physicochemical methods of analysis (extraction, infrared spectroscopy, and high-performance liquid chromatography) made it possible to establish the composition of priority PAHs of the oil shales and track changes occurring under thermal action. As a result of this work, it was shown that the yield of oil shale ash residues depended on the initial composition of oil shales and ranged from 5 to 82 wt % depending on the destruction temperature. The PAH content of the ash residues did not exceed 9.5 rel %.

Abstract Image

热过程模拟中西伯利亚油页岩多芳烃组成的变化
因此,本文介绍了Barzas (Barzassite)和Budagovo (Sapropelite)沉积物油页岩中多芳烃(PAHs)的研究结果,以及在T = 300、500和750°C的自由氧气条件下进行热破坏后获得的灰渣。一套物化分析方法(萃取、红外光谱、高效液相色谱)使得确定油页岩中优先多环芳烃的组成和跟踪热作用下的变化成为可能。结果表明,油页岩灰渣的产率取决于油页岩的初始成分,根据破坏温度的不同,产率在5% ~ 82%之间。灰渣中多环芳烃含量不超过9.5%。
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来源期刊
Solid Fuel Chemistry
Solid Fuel Chemistry CHEMISTRY, MULTIDISCIPLINARY-ENERGY & FUELS
CiteScore
1.10
自引率
28.60%
发文量
52
审稿时长
6-12 weeks
期刊介绍: The journal publishes theoretical and applied articles on the chemistry and physics of solid fuels and carbonaceous materials. It addresses the composition, structure, and properties of solid fuels. The aim of the published articles is to demonstrate how novel discoveries, developments, and theories may be used in improved analysis and design of new types of fuels, chemicals, and by-products. The journal is particularly concerned with technological aspects of various chemical conversion processes and includes papers related to geochemistry, petrology and systematization of fossil fuels, their beneficiation and preparation for processing, the processes themselves, and the ultimate recovery of the liquid or gaseous end products.
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