Experimental Study of Electric Conductivity of MPO3(M2WO4)–V2O5 (M = Na, K) Melts

IF 0.8 4区化学 Q4 CHEMISTRY, PHYSICAL

Russian Journal of Physical Chemistry A Pub Date : 2025-07-06 DOI:10.1134/S0036024425701067

A. M. Hasanaliev, P. N. Hasanalieva, A. I. Rasulov

引用次数: 0

Abstract

The electric conductivity of binary eutectic oxide–salt composites KPO₃–V₂O₅, NaPO₃–V₂O₅, Na₂WO₄–V₂O₅, and K₂WO₄–V₂O₅ has been studied. The behavior of the dependence of the conductivity logarithm and specific conductivity on the reciprocal temperature was determined. It was established that the 38 mol % NaPO₃–62 mol % V₂O₅ oxide–salt composite has the highest electric conductivity and is promising for use as an electrolyte for obtaining refractory metals and in chemical current sources.

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MPO3(M2WO4) -V2O5 （M = Na， K）熔体电导率的实验研究

研究了KPO3-V2O5、NaPO3-V2O5、Na2WO4-V2O5和K2WO4-V2O5二元共晶氧化物盐复合材料的电导率。测定了电导率对数和比电导率随温度倒数的变化规律。结果表明，38 mol %的NaPO3-62 mol %的V2O5氧化物盐复合材料具有最高的电导率，有望用作难熔金属的电解液和化学电流源。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Russian Journal of Physical Chemistry A 化学-物理化学

CiteScore

1.20

自引率

14.30%

发文量

376

审稿时长

5.1 months

期刊介绍： Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.