Influence of Thermal Reactions with α-Methylstyrene and Nitrobenzene on the Composition and Characteristics of the Anthracene Oil in Coal Tar

IF 0.5 Q4 ENGINEERING, CHEMICAL
A. P. Krasikova, E. I. Andreikov, D. O. Antonov, M. G. Pervova, E. F. Zhilina, K. A. Chistyakov
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引用次数: 0

Abstract

The change in composition and characteristics of anthracene oil from coal tar on reacting with hydrogen acceptors (α-methylstyrene and nitrobenzene) at 360°C is studied. Besides the formation of cumene and aniline by the transfer of hydrogen from the anthracene oil, α-methylstyrene and nitrobenzene react with components in the anthracene oil to form products that cannot be determined by chromatography. In addition, polymerization of the components in the anthracene oil is observed. The anthracene oil is analyzed after reaction with α-methylstyrene and nitrobenzene by means of gas–liquid chromatography, elemental analysis, thermogravimetric analysis, gel permeation chromatography, NMR 1H spectroscopy, IR spectroscopy, and UV fluorescent spectroscopy.

Abstract Image

α-甲基苯乙烯和硝基苯热反应对煤焦油中蒽油组成及特性的影响
研究了煤焦油中蒽油与氢受体(α-甲基苯乙烯和硝基苯)在360℃反应时的组成和特性变化。除蒽油中氢的转移生成异丙烯和苯胺外,α-甲基苯乙烯和硝基苯还与蒽油中的组分发生反应,生成无法用色谱法测定的产物。此外,观察了蒽油中各组分的聚合。采用气液色谱、元素分析、热重分析、凝胶渗透色谱、核磁共振1H光谱、红外光谱、紫外荧光光谱等方法对与α-甲基苯乙烯和硝基苯反应后的蒽油进行了分析。
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来源期刊
Coke and Chemistry
Coke and Chemistry ENGINEERING, CHEMICAL-
CiteScore
0.70
自引率
50.00%
发文量
36
期刊介绍: The journal publishes scientific developments and applications in the field of coal beneficiation and preparation for coking, coking processes, design of coking ovens and equipment, by-product recovery, automation of technological processes, ecology and economics. It also presents indispensable information on the scientific events devoted to thermal rectification, use of smokeless coal as an energy source, and manufacture of different liquid and solid chemical products.
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