Heterogeneous Hydrogenation and Isomerization of Carbocyclic Compounds of the Norbornene Series: A Review

IF 1.3 Q4 ENGINEERING, CHEMICAL
V. V. Zamalyutin, E. V. Okuneva, S. S. Moskvichev, V. R. Flid
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引用次数: 0

Abstract

The main laws and routes of the liquid-phase hydrogenation and isomerization of carbocyclic alkenes and dienes of the norbornene series in the presence of heterogeneous catalysts were systematized, and the reaction mechanisms were discussed. The reaction products were identified and the material balance was studied. Conditions for the hydrogenation and isomerization of the compounds were selected such as to provide the preservation of the norbornane framework. The reactivity of multiple bonds in norbornenes was assessed by experimental and quantum chemical methods. Adequate kinetic models of the processes in terms of the Langmuir–Hinshelwood approach and in the representation of multiple adsorption of substrates on a single active site were developed.

Abstract Image

降冰片烯系列碳环化合物的非均相加氢和异构化研究进展
系统研究了降冰片烯系列中碳环烯烃和二烯烃在非均相催化剂作用下液相加氢异构化的主要规律和途径,并对反应机理进行了探讨。对反应产物进行了鉴定,并对物料平衡进行了研究。选择化合物的氢化和异构化条件,以提供降冰片烷骨架的保存。采用实验和量子化学方法对降冰片烯中多键的反应性进行了评价。根据Langmuir-Hinshelwood方法和在单一活性位点上多次吸附底物的表示,开发了适当的过程动力学模型。
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来源期刊
Catalysis in Industry
Catalysis in Industry ENGINEERING, CHEMICAL-
CiteScore
1.30
自引率
14.30%
发文量
21
期刊介绍: The journal covers the following topical areas: Analysis of specific industrial catalytic processes: Production and use of catalysts in branches of industry: chemical, petrochemical, oil-refining, pharmaceutical, organic synthesis, fuel-energetic industries, environment protection, biocatalysis; technology of industrial catalytic processes (generalization of practical experience, improvements, and modernization); technology of catalysts production, raw materials and equipment; control of catalysts quality; starting, reduction, passivation, discharge, storage of catalysts; catalytic reactors.Theoretical foundations of industrial catalysis and technologies: Research, studies, and concepts : search for and development of new catalysts and new types of supports, formation of active components, and mechanochemistry in catalysis; comprehensive studies of work-out catalysts and analysis of deactivation mechanisms; studies of the catalytic process at different scale levels (laboratory, pilot plant, industrial); kinetics of industrial and newly developed catalytic processes and development of kinetic models; nonlinear dynamics and nonlinear phenomena in catalysis: multiplicity of stationary states, stepwise changes in regimes, etc. Advances in catalysis: Catalysis and gas chemistry; catalysis and new energy technologies; biocatalysis; nanocatalysis; catalysis and new construction materials.History of the development of industrial catalysis.
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