Effects of the use of bio-additives for fuel in metallic gasoline tanks

IF 2 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
Celic Cano Romero, Rogelio Cuevas García, Diego Adrián Fabila Bustos, Prisciliano Hernández Martínez, José R. Contreras Bárbara, Macaria Hernández Chávez
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引用次数: 0

Abstract

Bio-additives, generally composed of alcohol or esters, are sustainable substances added to fuels to enhance their properties and reduce CO2 emissions. In Mexico, there is a lack of regulations on bio-additive-gasoline mixture composition and effects this composition on the mechanical properties of the tanks is not clear. This study investigates the impact of the quantity of a bio-additive added to gasoline on metallic automotive and motorcycle tanks. Two experimental setups were developed: immersion tests in gasoline-bio-additive mixtures at varying concentrations of a sheet of automotive tanks, and exposure of motorcycle metallic tanks to ambient pressure–temperature conditions over 14 months. Corrosion signs and sediment accumulation appeared within 2 weeks, particularly in the 30% bio-additive mixture, pointing to compatibility issues. Characterization methods, including Raman spectroscopy, gas chromatography-mass spectrometry (GC–MS), Electron microscopy (SEM/EDS), and metallography, revealed methanol in the bio-additive composition. Methanol increases corrosion of the automotive sheets, also, it causes the removal of lead from the anticorrosion coating that covers the motorcycle tanks. This results, emphasize the compatibility challenges between bio-additives and all components of the metallic tanks.

生物添加剂对金属油箱燃料的影响
生物添加剂通常由酒精或酯类组成,是添加到燃料中以增强其性能和减少二氧化碳排放的可持续物质。在墨西哥,缺乏对生物添加剂-汽油混合物成分的规定,这种成分对油箱机械性能的影响尚不清楚。本文研究了汽油中生物添加剂的添加量对金属汽车和摩托车油箱的影响。研究人员开发了两种实验装置:一种是汽车油箱在不同浓度的汽油-生物添加剂混合物中浸泡测试,另一种是将摩托车金属油箱暴露在环境压力-温度条件下超过14个月。腐蚀迹象和沉积物积聚在2周内出现,特别是在30%的生物添加剂混合物中,表明相容性问题。表征方法包括拉曼光谱,气相色谱-质谱(GC-MS),电子显微镜(SEM/EDS)和金相分析,揭示了生物添加剂成分中的甲醇。甲醇增加了汽车板的腐蚀,同时,它会导致覆盖在摩托车油箱上的防腐涂层中的铅的去除。这一结果强调了生物添加剂与金属罐所有部件之间的兼容性挑战。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
8.60
自引率
0.00%
发文量
1
审稿时长
13 weeks
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