Synthesis of a Composite Material in Combustion Mode from a Mixture of Ti + 2B and Composite Ni–Al Particles with Different Ratios of Components

IF 0.3 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY
M. A. Ponomarev, V. E. Loryan, N. A. Kochetov
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引用次数: 0

Abstract—To obtain a composite with interpenetrating intermetallic/ceramic phases (of type IPC, interpenetrating phase composites) by the self-propagating high-temperature synthesis (SHS) method, the Ni–Al–Ti–2B powder system was used. It consisted of mechanically activated composite particles-granules (Ni + Al) and a mixture of finely dispersed boron and titanium powder. The quantitative ratio between the granules and the Ti + 2B mixture was varied. For all compositions, the synthesis was carried out in the combustion mode without heating. In the combustion wave front, the chemical reactions occurred in the composite granules and in the mixture around the granules, between titanium and boron. As a result of combustion a porous framework of titanium diboride was formed; a melt of nickel aluminides penetrated into the pores of the framework. The metal–ceramic combustion product is characterized by developed porosity and a composite structure with diboride and intermetallic phases located like interpenetrating frameworks. The TiB2–NiAl structure depends on the ratio of components in the mixture. The pores formed in place of the granules, repeating their shape.

Abstract Image

Ti + 2B与不同组分比的Ni-Al复合颗粒燃烧合成复合材料
摘要:采用Ni-Al-Ti-2B粉末体系,采用自传播高温合成(SHS)方法制备了具有互穿相的金属间/陶瓷相复合材料(IPC型互穿相复合材料)。它由机械活化的复合颗粒-颗粒(Ni + Al)和精细分散的硼和钛粉的混合物组成。颗粒与Ti + 2B混合物的定量比例不同。所有组合物的合成均在燃烧模式下进行,没有加热。在燃烧波前,复合颗粒和颗粒周围的混合物中钛和硼发生化学反应。燃烧形成多孔的二硼化钛骨架;镍铝化物的熔体渗透到框架的孔隙中。金属-陶瓷燃烧产物具有气孔发育、二硼化物相和金属间相呈互穿框架状的复合结构。TiB2-NiAl的结构取决于混合物中各组分的比例。孔隙在颗粒的位置形成,重复它们的形状。
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来源期刊
Inorganic Materials: Applied Research
Inorganic Materials: Applied Research Engineering-Engineering (all)
CiteScore
0.90
自引率
0.00%
发文量
199
期刊介绍: Inorganic Materials: Applied Research  contains translations of research articles devoted to applied aspects of inorganic materials. Best articles are selected from four Russian periodicals: Materialovedenie, Perspektivnye Materialy, Fizika i Khimiya Obrabotki Materialov, and Voprosy Materialovedeniya  and translated into English. The journal reports recent achievements in materials science: physical and chemical bases of materials science; effects of synergism in composite materials; computer simulations; creation of new materials (including carbon-based materials and ceramics, semiconductors, superconductors, composite materials, polymers, materials for nuclear engineering, materials for aircraft and space engineering, materials for quantum electronics, materials for electronics and optoelectronics, materials for nuclear and thermonuclear power engineering, radiation-hardened materials, materials for use in medicine, etc.); analytical techniques; structure–property relationships; nanostructures and nanotechnologies; advanced technologies; use of hydrogen in structural materials; and economic and environmental issues. The journal also considers engineering issues of materials processing with plasma, high-gradient crystallization, laser technology, and ultrasonic technology. Currently the journal does not accept direct submissions, but submissions to one of the source journals is possible.
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