Zinc Removal from Wastewater by Emulsion Liquid Membrane Technique: Utilizing Response Surface Methodology to Improve Optimization and Analyze Data

IF 1.1 4区 工程技术 Q3 CHEMISTRY, ORGANIC
Ahmed Salah Al-Shati, Hussein Hantoosh Alaydamee, Abbas J. Sultan, Zahraa W. Hasan, Bashar J. Kadhim, Laith S. Sabri, Hasan Sh. Majdi
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Abstract

Metals’ potential hazards have drawn greater attention to the influence of metal pollution on water, making it a crucial subject of study in recent environmental research. This research aligns with the Sustainable Development Goals (SDGs), that aim to protect the world by addressing environmental concerns. As a consequence, understanding the impact of metal pollution on water is an essential aspect of the SDGs’ efforts to improve environmental preservation. This study provides insight into the removal of zinc ions from industrial wastewater using emulsion liquid membrane (ELM) technology. A study was conducted to investigate the use of ELM technology for removing zinc ions from industrial wastewater. Previous studies have shown that ELM can easily remove metals in their ionic form, but the presence of other organic or inorganic compounds like sulfates, phosphates, and carbonates in industrial wastewater increases their solubility and complexity of the removal. To develop the liquid membrane, a surfactant called Sorbitan monooleate (Span 80), an extractant called bis-2-ethylhexyl phosphoric acid (D2EHPA), hydrogen chloride as a reagent, and kerosene as a diluent were used. The study investigated the impact of surfactant concentration, homogenizer speed, extractant concentration, and external phase pH on zinc ion removal using a Box-Behnken design based on Response Surface Methodology (RSM). The results showed that surfactant concentration and pH had the greatest impact on removal efficiency, while homogenizer speed and surfactant extractant had a lower impact on zinc removal. The investigation adjusted numerous parameters to achieve a zinc recovery rate of more than 93% from the bioleaching solution. The most beneficial conditions were a stirring speed of 250 rpm for 10 min, 4.75% v/v Span 80, a homogenizer speed of 11 212 rpm for 8 min, a feed phase pH of 5 or 4.9, and 6% v/v D2EHPA in kerosene.

Abstract Image

乳状液膜法除锌废水:利用响应面法改进优化及数据分析
金属的潜在危害引起了人们对金属污染对水体影响的关注,成为近年来环境研究的一个重要课题。这项研究与可持续发展目标(sdg)一致,旨在通过解决环境问题来保护世界。因此,了解金属污染对水的影响是可持续发展目标努力改善环境保护的一个重要方面。本研究为乳状液膜(ELM)技术去除工业废水中的锌离子提供了新的思路。研究了利用ELM技术去除工业废水中的锌离子。先前的研究表明,ELM可以很容易地去除离子形式的金属,但工业废水中其他有机或无机化合物(如硫酸盐、磷酸盐和碳酸盐)的存在增加了它们的溶解度和去除的复杂性。为了形成液体膜,使用了表面活性剂山梨醇单油酸酯(Span 80),萃取剂双-2-乙基己基磷酸(D2EHPA),氯化氢作为试剂,煤油作为稀释剂。采用基于响应面法(RSM)的Box-Behnken设计,研究了表面活性剂浓度、均质机速度、萃取剂浓度和外相pH对锌离子去除的影响。结果表明,表面活性剂浓度和pH对锌的去除率影响最大,均质机转速和表面活性剂萃取剂对锌的去除率影响较小。该研究调整了许多参数,使生物浸出液的锌回收率达到93%以上。最有利的条件是搅拌速度为250 rpm,搅拌10 min, 4.75% v/v Span 80,均质机转速为11 212 rpm,搅拌8 min,进料相pH为5或4.9,煤油中D2EHPA浓度为6% v/v。
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来源期刊
Petroleum Chemistry
Petroleum Chemistry 工程技术-工程:化工
CiteScore
2.50
自引率
21.40%
发文量
102
审稿时长
6-12 weeks
期刊介绍: Petroleum Chemistry (Neftekhimiya), founded in 1961, offers original papers on and reviews of theoretical and experimental studies concerned with current problems of petroleum chemistry and processing such as chemical composition of crude oils and natural gas liquids; petroleum refining (cracking, hydrocracking, and catalytic reforming); catalysts for petrochemical processes (hydrogenation, isomerization, oxidation, hydroformylation, etc.); activation and catalytic transformation of hydrocarbons and other components of petroleum, natural gas, and other complex organic mixtures; new petrochemicals including lubricants and additives; environmental problems; and information on scientific meetings relevant to these areas. Petroleum Chemistry publishes articles on these topics from members of the scientific community of the former Soviet Union.
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