Synthesis and Evaluation of Silicon-Containing Acridine Photocatalysts

IF 3 4区化学 Q3 CHEMISTRY, PHYSICAL

ChemPhotoChem Pub Date : 2025-06-29 DOI:10.1002/cptc.202500138

Liubov O. Kupriyanets, Mikhail O. Zubkov, Mikhail D. Kosobokov, Alexander D. Dilman

引用次数: 0

Abstract

A protocol for the synthesis of sterically hindered 9-silylacridines via lithiation/silylation sequence is developed. The photocatalytic efficiency of obtained acridines is tested in a variety of decarboxylative processes and compared with the properties of aryl- and alkyl-substituted analogs. To explain the observations, quantum chemical calculations are carried out, revealing the features of the spatial structures of these molecules.

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含硅吖啶光催化剂的合成与评价

提出了一种通过锂化/硅基化顺序合成空间位阻9-硅基吖啶的方法。在各种脱羧过程中测试了所得吖啶的光催化效率，并与芳基和烷基取代类似物的性质进行了比较。为了解释这些观察结果，进行了量子化学计算，揭示了这些分子的空间结构特征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ChemPhotoChem Chemistry-Physical and Theoretical Chemistry

CiteScore

5.80

自引率

5.40%

发文量

165

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