{"title":"Sodium Borohydride-Assisted Catalytic Property of BiOCl Nanoparticles for Water Remediation","authors":"Ratna Sarkar, Dimitra Das, Subrata Sarkar, Kalyan Kumar Chattopadhyay","doi":"10.1002/cnma.202500148","DOIUrl":null,"url":null,"abstract":"<p>The fundamental metal oxyhalides’ chemical catalytic property in converting 4-nitrophenol to 4-aminophenol is observed. The degradation efficiency for the most effective sample is about 100%, and the rate kinetics is 1.88 min<sup>−1</sup> within a 4-min interval. The transformation is performed at ambient temperature and in the aqueous sodium borohydride solution. This study reports an easy, cost-effective, and eco-friendly hydrothermal synthesis of bismuth oxychloride (BiOCl) nanomaterials. In addition to the synthesis assertions, various sophisticated techniques are being used to investigate nanomaterials’ optical and electronic properties. The tunability of band formation and phase equilibrium of nanomaterials and the relationship between nanomaterials and catalytic activity are examined. The synthesized nanomaterials are very valuable for wastewater remediation in the aquatic environment.</p>","PeriodicalId":54339,"journal":{"name":"ChemNanoMat","volume":"11 9","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemNanoMat","FirstCategoryId":"88","ListUrlMain":"https://aces.onlinelibrary.wiley.com/doi/10.1002/cnma.202500148","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The fundamental metal oxyhalides’ chemical catalytic property in converting 4-nitrophenol to 4-aminophenol is observed. The degradation efficiency for the most effective sample is about 100%, and the rate kinetics is 1.88 min−1 within a 4-min interval. The transformation is performed at ambient temperature and in the aqueous sodium borohydride solution. This study reports an easy, cost-effective, and eco-friendly hydrothermal synthesis of bismuth oxychloride (BiOCl) nanomaterials. In addition to the synthesis assertions, various sophisticated techniques are being used to investigate nanomaterials’ optical and electronic properties. The tunability of band formation and phase equilibrium of nanomaterials and the relationship between nanomaterials and catalytic activity are examined. The synthesized nanomaterials are very valuable for wastewater remediation in the aquatic environment.
ChemNanoMatEnergy-Energy Engineering and Power Technology
CiteScore
6.10
自引率
2.60%
发文量
236
期刊介绍:
ChemNanoMat is a new journal published in close cooperation with the teams of Angewandte Chemie and Advanced Materials, and is the new sister journal to Chemistry—An Asian Journal.