{"title":"Kinetics of Phosphate Ion Sorption by Layered Double Magnesium Aluminum Hydroxide","authors":"D. V. Maiorov","doi":"10.1134/S0040579525700411","DOIUrl":null,"url":null,"abstract":"<p>The paper presents the results of studies of the sorption properties of layered double hydroxide of the composition Mg<sub>4</sub>Al<sub>2</sub>(OH)<sub>12</sub>CO<sub>3</sub>⋅3H<sub>2</sub>O, obtained by the solid-phase interaction method, with respect to the <span>\\({\\text{PO}}_{4}^{{3 - }}\\)</span> ion. It is found that the sorption process is most adequately described by the Langmuir monomolecular adsorption equation, and its kinetics is described by a pseudo-first-order equation. The activation energy of the process is determined, based on which is concluded that the process occurs in the diffusion region.</p>","PeriodicalId":798,"journal":{"name":"Theoretical Foundations of Chemical Engineering","volume":"59 2","pages":"238 - 245"},"PeriodicalIF":0.6000,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical Foundations of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0040579525700411","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The paper presents the results of studies of the sorption properties of layered double hydroxide of the composition Mg4Al2(OH)12CO3⋅3H2O, obtained by the solid-phase interaction method, with respect to the \({\text{PO}}_{4}^{{3 - }}\) ion. It is found that the sorption process is most adequately described by the Langmuir monomolecular adsorption equation, and its kinetics is described by a pseudo-first-order equation. The activation energy of the process is determined, based on which is concluded that the process occurs in the diffusion region.
期刊介绍:
Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.