{"title":"Conversion of Sulfocationite from \\({\\text{NH}}_{4}^{ + }\\) Form to H+ Form","authors":"E. P. Lokshin, O. A. Tareeva","doi":"10.1134/S0040579525700526","DOIUrl":null,"url":null,"abstract":"<p>The conversion of sulfocationite from the <span>\\({\\text{NH}}_{4}^{ + }\\)</span> form to the H<sup>+</sup> form is studied. It is shown that when using concentrated solutions of strong mineral acids (nitric, sulfuric), the conversion is ineffective. In order to achieve efficient conversion to the H<sup>+</sup> form, it is recommended to treat the sulfocationite in the <span>\\({\\text{NH}}_{4}^{ + }\\)</span> form in two stages: first with a sodium salt solution to convert it to the intermediate Na<sup>+</sup> form, then with a strong mineral acid solution to obtain the sorbent in the H<sup>+</sup> form. An equation is proposed for calculating the specific reagent consumption required to achieve a certain degree of the sorbent conversion.</p>","PeriodicalId":798,"journal":{"name":"Theoretical Foundations of Chemical Engineering","volume":"59 2","pages":"314 - 318"},"PeriodicalIF":0.6000,"publicationDate":"2025-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Theoretical Foundations of Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1134/S0040579525700526","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The conversion of sulfocationite from the \({\text{NH}}_{4}^{ + }\) form to the H+ form is studied. It is shown that when using concentrated solutions of strong mineral acids (nitric, sulfuric), the conversion is ineffective. In order to achieve efficient conversion to the H+ form, it is recommended to treat the sulfocationite in the \({\text{NH}}_{4}^{ + }\) form in two stages: first with a sodium salt solution to convert it to the intermediate Na+ form, then with a strong mineral acid solution to obtain the sorbent in the H+ form. An equation is proposed for calculating the specific reagent consumption required to achieve a certain degree of the sorbent conversion.
期刊介绍:
Theoretical Foundations of Chemical Engineering is a comprehensive journal covering all aspects of theoretical and applied research in chemical engineering, including transport phenomena; surface phenomena; processes of mixture separation; theory and methods of chemical reactor design; combined processes and multifunctional reactors; hydromechanic, thermal, diffusion, and chemical processes and apparatus, membrane processes and reactors; biotechnology; dispersed systems; nanotechnologies; process intensification; information modeling and analysis; energy- and resource-saving processes; environmentally clean processes and technologies.