{"title":"IoT integrated quantile principal component analysis based framework for toxic pesticides recognition and classification","authors":"Kanak Kumar , Anshul Verma , Pradeepika Verma","doi":"10.1016/j.comtox.2025.100375","DOIUrl":null,"url":null,"abstract":"<div><div>Pesticides present significant concerns regarding environmental sustainability and global stability. This study investigates the types, benefits, and environmental challenges associated with pesticide use. To address these concerns, we developed an innovative Internet of Things (IoT) integrated quantile principal component analysis (QPCA) framework for the recognition of toxic pesticides in smart farming, termed IoT-TPR. The proposed IoT-TPR system is an intelligent electronic nose based on a tin-oxide sensor array, consisting of eight commercial metal–oxide–semiconductor gas sensors, which detect toxic pesticides and transmit the data to the Amazon Web Services cloud for further analysis. A two-stage QPCA preprocessing technique is employed to analyze sensor responses. Subsequently, four classifiers such as radial basis function (RBF), extreme learning machine (ELM), decision tree (DT), and k-nearest neighbor (KNN) are used for comparative performance evaluation. The results indicate that QPCA-KNN achieves the highest accuracy at 99.05%, outperforming other methods across all performance metrics and demonstrating superior classification capability. RBF (96.24%) and ELM (95.81%) also exhibit strong performance, though slightly lower than QPCA-KNN, while DT (92.35%) shows the lowest accuracy but still maintains reasonable performance. Overall, QPCA-KNN emerges as the most effective and robust classification model in this study.</div></div>","PeriodicalId":37651,"journal":{"name":"Computational Toxicology","volume":"36 ","pages":"Article 100375"},"PeriodicalIF":2.9000,"publicationDate":"2025-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Computational Toxicology","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2468111325000350","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"TOXICOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
Pesticides present significant concerns regarding environmental sustainability and global stability. This study investigates the types, benefits, and environmental challenges associated with pesticide use. To address these concerns, we developed an innovative Internet of Things (IoT) integrated quantile principal component analysis (QPCA) framework for the recognition of toxic pesticides in smart farming, termed IoT-TPR. The proposed IoT-TPR system is an intelligent electronic nose based on a tin-oxide sensor array, consisting of eight commercial metal–oxide–semiconductor gas sensors, which detect toxic pesticides and transmit the data to the Amazon Web Services cloud for further analysis. A two-stage QPCA preprocessing technique is employed to analyze sensor responses. Subsequently, four classifiers such as radial basis function (RBF), extreme learning machine (ELM), decision tree (DT), and k-nearest neighbor (KNN) are used for comparative performance evaluation. The results indicate that QPCA-KNN achieves the highest accuracy at 99.05%, outperforming other methods across all performance metrics and demonstrating superior classification capability. RBF (96.24%) and ELM (95.81%) also exhibit strong performance, though slightly lower than QPCA-KNN, while DT (92.35%) shows the lowest accuracy but still maintains reasonable performance. Overall, QPCA-KNN emerges as the most effective and robust classification model in this study.
期刊介绍:
Computational Toxicology is an international journal publishing computational approaches that assist in the toxicological evaluation of new and existing chemical substances assisting in their safety assessment. -All effects relating to human health and environmental toxicity and fate -Prediction of toxicity, metabolism, fate and physico-chemical properties -The development of models from read-across, (Q)SARs, PBPK, QIVIVE, Multi-Scale Models -Big Data in toxicology: integration, management, analysis -Implementation of models through AOPs, IATA, TTC -Regulatory acceptance of models: evaluation, verification and validation -From metals, to small organic molecules to nanoparticles -Pharmaceuticals, pesticides, foods, cosmetics, fine chemicals -Bringing together the views of industry, regulators, academia, NGOs