A new high-toughness Co-based nanocrystalline soft-magnetic alloy capable of large stress-induced anisotropy

IF 5.6 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
N.M. Bruno , V. Keylin , G. Feichter , A.M. Leary , R.D. Noebe
{"title":"A new high-toughness Co-based nanocrystalline soft-magnetic alloy capable of large stress-induced anisotropy","authors":"N.M. Bruno ,&nbsp;V. Keylin ,&nbsp;G. Feichter ,&nbsp;A.M. Leary ,&nbsp;R.D. Noebe","doi":"10.1016/j.scriptamat.2025.116998","DOIUrl":null,"url":null,"abstract":"<div><div>Mechanical and magnetic properties for a new Co-base nanocrystalline soft magnetic alloy, Co<sub>80</sub>Fe<sub>1.5</sub>Mn<sub>1.5</sub>Nb<sub>8</sub>Si<sub>2</sub>B<sub>7</sub> at.%, are compared to those of previously studied Co<sub>(80–2x)</sub>-Fe<sub>x</sub>−Mn<sub>x</sub>-Nb<sub>4</sub>-Si<sub>2</sub>-B<sub>14</sub> at.% (where <em>x</em> = 2.3, 2.7, and 4) as cast and stress-annealed ribbons. The new alloy exhibits a fracture toughness,<span><math><mrow><mspace></mspace><msub><mi>K</mi><mi>C</mi></msub></mrow></math></span>, of 58 MPa<span><math><msqrt><mi>m</mi></msqrt></math></span> after stress-annealing at 500 °C and a stress-induced/stress-normalized magnetic anisotropy, <span><math><mrow><msub><mi>K</mi><mi>u</mi></msub><mo>/</mo><mi>σ</mi></mrow></math></span>, of 0.094 kJ/(MPa<span><math><mrow><mo>·</mo><msup><mrow><mi>m</mi></mrow><mn>3</mn></msup></mrow></math></span>), i.e., a value nearly double that of other Co-base nanocrystalline alloys. The bulk magnetostriction, <span><math><msubsup><mi>λ</mi><mi>s</mi><mrow><mi>b</mi><mi>u</mi><mi>l</mi><mi>k</mi></mrow></msubsup></math></span>, of the new composition was also determined to be approximately zero after stress-annealing. XRD was used to identify the nanocrystalline phases in annealed ribbon, and the fracture morphologies were observed via SEM. The fracture surfaces of tough and brittle annealed ribbons contained morphologies indicative of local melting and traditional shear hackle/mist patterns, respectively, suggesting that the iron and manganese concentrations in Co-based nanocomposites influence the alloy’s mechanical properties and processability.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"271 ","pages":"Article 116998"},"PeriodicalIF":5.6000,"publicationDate":"2025-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225004609","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Mechanical and magnetic properties for a new Co-base nanocrystalline soft magnetic alloy, Co80Fe1.5Mn1.5Nb8Si2B7 at.%, are compared to those of previously studied Co(80–2x)-Fex−Mnx-Nb4-Si2-B14 at.% (where x = 2.3, 2.7, and 4) as cast and stress-annealed ribbons. The new alloy exhibits a fracture toughness,KC, of 58 MPam after stress-annealing at 500 °C and a stress-induced/stress-normalized magnetic anisotropy, Ku/σ, of 0.094 kJ/(MPa·m3), i.e., a value nearly double that of other Co-base nanocrystalline alloys. The bulk magnetostriction, λsbulk, of the new composition was also determined to be approximately zero after stress-annealing. XRD was used to identify the nanocrystalline phases in annealed ribbon, and the fracture morphologies were observed via SEM. The fracture surfaces of tough and brittle annealed ribbons contained morphologies indicative of local melting and traditional shear hackle/mist patterns, respectively, suggesting that the iron and manganese concentrations in Co-based nanocomposites influence the alloy’s mechanical properties and processability.

Abstract Image

具有大应力诱导各向异性的新型高韧性钴基纳米晶软磁合金
新型钴基纳米晶软磁合金Co80Fe1.5Mn1.5Nb8Si2B7 at的机械和磁性能。%,与先前研究的Co(80-2x)-Fex−Mnx-Nb4-Si2-B14 at相比较。%(其中x = 2.3, 2.7和4)为铸造和应力退火带。500℃应力退火后,合金的断裂韧性KC为58 MPam,应力诱导/应力归一化磁各向异性Ku/σ为0.094 kJ/(MPa·m3),几乎是其他钴基纳米晶合金的两倍。经应力退火后,新材料的体磁致伸缩λsbulk近似为零。采用XRD对退火带材的纳米晶相进行了表征,并通过SEM对断口形貌进行了观察。退火后的韧带断口和脆带断口分别具有表明局部熔化和传统剪切锯齿/雾状的形貌,这表明co基纳米复合材料中的铁和锰浓度影响合金的力学性能和可加工性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Scripta Materialia
Scripta Materialia 工程技术-材料科学:综合
CiteScore
11.40
自引率
5.00%
发文量
581
审稿时长
34 days
期刊介绍: Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信