{"title":"Correlations for the Temperature Dependent Viscosity of Saturated Liquids","authors":"Cuihua Zhang, Xiaobing Liu, Jianxiang Tian, Shangguo Yang, Hua Jiang","doi":"10.1134/S0036024425701456","DOIUrl":null,"url":null,"abstract":"<p>The Arrhenius correlation, the Vogel–Fulcher–Tamman correlation and a four-parameter correlation for the temperature dependent viscosity are compared and checked for saturated liquids by using the viscosity data in the NIST database. 52 substances including hydrocarbons, refrigerants, and some others are considered. By comparing the calculated numerical results from the three correlations with the data from the NIST database, it is found that the four-parameter correlation can predict the NIST data with average absolute deviation (AAD) less than 5% for all the 52 liquids, AAD less than 1% for 39 liquids. Better accuracy of the four-parameter correlation compared to the Arrhenius correlation and the Vogel–Fulcher–Tamman correlation is found.</p>","PeriodicalId":767,"journal":{"name":"Russian Journal of Physical Chemistry A","volume":"99 9","pages":"2012 - 2021"},"PeriodicalIF":0.8000,"publicationDate":"2025-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Physical Chemistry A","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0036024425701456","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The Arrhenius correlation, the Vogel–Fulcher–Tamman correlation and a four-parameter correlation for the temperature dependent viscosity are compared and checked for saturated liquids by using the viscosity data in the NIST database. 52 substances including hydrocarbons, refrigerants, and some others are considered. By comparing the calculated numerical results from the three correlations with the data from the NIST database, it is found that the four-parameter correlation can predict the NIST data with average absolute deviation (AAD) less than 5% for all the 52 liquids, AAD less than 1% for 39 liquids. Better accuracy of the four-parameter correlation compared to the Arrhenius correlation and the Vogel–Fulcher–Tamman correlation is found.
期刊介绍：
Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world.
Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
