Numerical analysis on the thermal stress and dislocation density of a 300 mm SiC single crystal grown by the PVT method

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
CrystEngComm Pub Date : 2025-07-31 DOI:10.1039/D5CE00471C
Sheng'ou Lu, Binjie Xu, Lingling Xuan, Anqi Wang, Pengyang Chen, Fan Wang, Xiaodong Pi, Deren Yang and Xuefeng Han
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引用次数: 0

Abstract

The expansion of the diameter of a SiC single crystal to 300 mm represents a significant milestone in the technological development of SiC crystal growth. However, growing a 300 mm SiC crystal with the method of physical vapor transport (PVT) poses substantial challenges primarily owing to thermal stress and dislocation multiplication, both of which are intrinsically related to crystal quality. This study employs numerical simulations to investigate thermal stress, resolved shear stress (RSS) on the basal and prismatic planes, and the density of basal plane dislocations (BPDs) in a 300 mm SiC single crystal. Key factors such as the off-axis growth, high-temperature creep, and thermal stress relaxation are considered with comparison to those for a 200 mm SiC single crystal. The results indicate that prismatic slip and BPD density in a 300 mm SiC single crystal further increases.

Abstract Image

PVT法生长300 mm SiC单晶的热应力和位错密度的数值分析
SiC单晶直径扩展到300毫米是SiC晶体生长技术发展的一个重要里程碑。然而,用物理气相输运(PVT)方法生长300 mm的SiC晶体面临着巨大的挑战,主要是由于热应力和位错倍增,这两者都与晶体质量本质上有关。本研究采用数值模拟方法研究了300 mm SiC单晶的热应力、基面和棱柱面分解剪切应力(RSS)以及基面位错密度(bpd)。考虑了离轴生长、高温蠕变和热应力松弛等关键因素,并与200 mm SiC单晶进行了比较。结果表明,300 mm SiC单晶的棱柱滑移和BPD密度进一步增加。
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来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
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