Peng Meng, Feng Gao, Bo Wu, Jiaqi Peng, Lei Zeng, Jingsan Xu, Daigo Miyajima, Parvej Alam, Ben Zhong Tang* and Zijie Qiu*,
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引用次数: 0
Abstract
The polymerization mechanism and the identification of key oligomer intermediates during the thermal condensation of benzoguanamine (BG) remain unclear. Herein, we report a novel mixed thermal condensation strategy using BG and a pre-synthesized dimer to selectively synthesize the trimer (BG)3 with a significantly enhanced yield. Comprehensive characterization techniques confirm the formation of a linear molecular structure for (BG)3. Notably, (BG)3 exhibits a high molar absorption coefficient, approximately double the dimer and 4-fold greater than the monomer. Notably, (BG)3 demonstrates crystallization-induced phosphorescence (CIP) with a lifetime of 514.9 μs in the crystalline state at room temperature.
期刊介绍：
Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.
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