Endogenous, yet Exotic, Sulfur in the Lunar Mantle

IF 4 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
J. W. Dottin III, S. B. Simon, C. K. Shearer, J. Benson, H. Fu, J. S. Boesenberg, B. Monteleone, the ANGSA Science Team
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引用次数: 0

Abstract

In situ sulfur isotope analyses of sulfides found in regolith particles from the recently opened Apollo 17 drive tube 73001/2 reveal variable 34S/32S and 33S/32S that range from that of typical lunar basalts to strongly 34S- and 33S-depleted values (δ34S = −4.1 ± 0.35 to +1.5 ± 0.029; Δ33S = −2.8 ± 0.48 to −0.1 ± 0.27 (2σ)). All Δ33S and δ34S data are positively correlated. The correlation indicates mixing between at least two distinct sources of sulfur in the lunar mantle, one of which is associated with photochemically processed sulfur from a gaseous environment (strongly negative Δ33S). The gaseous precursor and its preservation in endogenous sulfides require that either the sulfur was delivered to the lunar mantle early in its history through unknown processes or it is a remnant of the giant Moon-forming impactor.

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月球地幔中的内生而又外来的硫
对最近打开的阿波罗17号驱动管73001/2中风化层颗粒中硫化物的原位硫同位素分析显示,34S/32S和33S/32S变化范围从典型的月球玄武岩到强烈的34S和33S损耗值(δ34S =−4.1±0.35至+1.5±0.029;Δ33S =−2.8±0.48至−0.1±0.27 (2σ))。所有Δ33S与δ34S数据均呈正相关。这种相关性表明,月幔中至少有两种不同来源的硫混合在一起,其中一种与气体环境中经过光化学处理的硫有关(强烈负的Δ33S)。气态前体及其在内源性硫化物中的保存要求,要么硫在其历史的早期通过未知的过程被传递到月球地幔,要么它是巨大的月球形成撞击物的残留物。
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来源期刊
Journal of Geophysical Research: Planets
Journal of Geophysical Research: Planets Earth and Planetary Sciences-Earth and Planetary Sciences (miscellaneous)
CiteScore
8.00
自引率
27.10%
发文量
254
期刊介绍: The Journal of Geophysical Research Planets is dedicated to the publication of new and original research in the broad field of planetary science. Manuscripts concerning planetary geology, geophysics, geochemistry, atmospheres, and dynamics are appropriate for the journal when they increase knowledge about the processes that affect Solar System objects. Manuscripts concerning other planetary systems, exoplanets or Earth are welcome when presented in a comparative planetology perspective. Studies in the field of astrobiology will be considered when they have immediate consequences for the interpretation of planetary data. JGR: Planets does not publish manuscripts that deal with future missions and instrumentation, nor those that are primarily of an engineering interest. Instrument, calibration or data processing papers may be appropriate for the journal, but only when accompanied by scientific analysis and interpretation that increases understanding of the studied object. A manuscript that describes a new method or technique would be acceptable for JGR: Planets if it contained new and relevant scientific results obtained using the method. Review articles are generally not appropriate for JGR: Planets, but they may be considered if they form an integral part of a special issue.
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