Biofabrication of Titanium Dioxide Nanoparticles using Syzygium samarangense Extracts: Characterization and Evaluation of their Photocatalytic Activity

IF 1.1 4区 化学 Q4 CHEMISTRY, PHYSICAL
Ganapathy Aarthe,  Periyasamy Anitha, Sivamaruthamuthu Nandhini
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Abstract

The research work presents the eco-friendly synthesis of titanium dioxide (TiO2) nanoparticles using an aqueous extract of Syzygium samarangense through a green synthesis approach. The biofabricated TiO2 nanoparticles were characterized using various techniques, including Field Emission Scanning Electron Microscopy, which revealed a distinctive ball-like morphology. The crystalline size of nanomaterials were determined by X-ray diffraction method. Ultraviolet spectroscopy analysis indicates band gap energy of 3.1 eV, which confirms that nanoparticles are suitable for photocatalytic applications. Phytochemical analysis of the Syzygium samarangense extract demonstrated the presence of key biomolecules such as alkaloids and phenolic compounds, which likely played a crucial role in nanoparticles synthesis and stabilization. The photocatalytic activity of the synthesized TiO2 nanoparticles was evaluated using methylene blue dye degradation under ultraviolet light. The nanoparticles exhibited significant photocatalytic efficiency, with a marked decrease in methylene blue concentration over time, highlighting their potential for environmental remediation. These results demonstrate the viability of green-synthesized TiO2 nanoparticles for photocatalytic applications, offering a sustainable alternative to conventional methods of nanoparticles fabrication.

Abstract Image

Abstract Image

利用皂荚提取物制备二氧化钛纳米颗粒:表征及其光催化活性评价
本研究采用绿色合成的方法,利用沙马根水提物对二氧化钛(TiO2)纳米粒子进行了生态合成。利用各种技术(包括场发射扫描电子显微镜)对生物制备的TiO2纳米颗粒进行了表征,发现其具有独特的球状形态。采用x射线衍射法测定了纳米材料的晶体尺寸。紫外光谱分析表明,带隙能为3.1 eV,证实了纳米颗粒适合于光催化应用。植物化学分析表明,沙马根提取物中存在生物碱和酚类化合物等关键生物分子,它们可能在纳米颗粒的合成和稳定中起着至关重要的作用。利用亚甲基蓝染料在紫外光下降解TiO2纳米粒子,评价了其光催化活性。纳米颗粒表现出显著的光催化效率,随着时间的推移,亚甲基蓝浓度显著降低,突出了它们在环境修复方面的潜力。这些结果证明了绿色合成的TiO2纳米颗粒光催化应用的可行性,为传统的纳米颗粒制造方法提供了一种可持续的替代方法。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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