Magmatic Cl-H2O contents, fluid extraction and porphyry fertility: Evidence from zircon and its apatite inclusions

IF 5 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS
Wenting Huang, Madeleine C.S. Humphreys, David J. Colby, Michael J. Stock, Jian Zhang, Zexian Cui, Xiao-Ping Xia, Jingjing Zhu, Juan Liao, Huaying Liang
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引用次数: 0

Abstract

The formation of giant porphyry deposits requires the accumulation of up to billions of tons of volatiles (H2O, Cl, and S) in an evolving trans-crustal magma system, followed by their focused release to the hydrothermal system via volatile exsolution in the upper crustal magma chamber. However, it remains unclear whether ore-forming and ore-barren magmatic pulses derived from the same parental magma system differ in initial volatile compositions or exsolution conditions. This uncertainty hinders our comprehension of how massive volatiles enrich and deliver the key drivers of porphyry mineralization. In this work, we investigate zircon water contents and zircon-hosted apatite volatile compositions of the pre-ore (109.7 ± 0.8 Ma), syn-ore (103.1 ± 1.1 Ma), and post-ore (98.1 ± 1.1 Ma) intrusions of the Zijinshan ore field (ZOF). These data, along with numerical modelling, allow us to illustrate the volatile evolution of the magmatic system which sourced the largest Cretaceous porphyry Cu-Mo deposit in South China. Although geochemically similar, these co-sourced magmas exhibit distinct volatile compositions and evolution patterns. Zircon-hosted apatite inclusions from the syn-ore porphyry show highly variable Cl (0.14–2.94 wt%) and F (0.04–3.37 wt%) contents, whereas apatite from the pre-ore and post-ore intrusions displays more restricted halogen variation (0.62–2.70 wt% Cl, and 0.41–1.56 wt% F). Numerical modelling of apatite evolutionary trends suggests that the syn-ore magma had the highest initial melt H2O (∼5.0 wt%) and Cl (∼1300 ppm) contents, exsolving fluids with average aggregated salinity of 3.24 ± 0.57 wt% NaCleq at the deepest level. These results align with the zircon OH contents and biotite Al-thermobarometers, which indicate the highest saturation pressure (∼211 MPa) for the syn-ore porphyry. We suggest that fluid exsolution from magma with moderate Cl content at > 200 MPa optimises Cl-Cu extraction efficiency and promotes the formation of connected fluid networks throughout the magma chamber, facilitating upward fluid migration and subsequent mineralisation. In contrast, modelling indicates that the pre-ore magma had an intermediate initial melt H2O (∼ 4.0 wt%) but the lowest Cl (∼700 ppm) contents, generating less saline fluids (< 3.0 wt% NaCleq), which hampered metal extraction. The post-ore magma, despite relatively high initial Cl (∼1100 ppm) and comparable fluid salinity (3.36 ± 1.40 wt% NaCleq), had the lowest H2O (3.72 ± 0.70 wt%) and saturated at the lowest pressure (∼78 MPa), limiting Cu extraction, exsolved fluid amount, and focused fluid flux. Our findings indicate that the syn-ore volatile enrichment occurred primarily within the lower-crustal magma reservoir. In the absence of isotopic evidence for direct mafic recharge, we propose that fluids derived from underplating mafic magmas, rather than direct magma mixing, provided the critical volatile budget required for the ZOF porphyry mineralisation.
岩浆Cl-H2O含量、流体萃取与斑岩肥力:来自锆石及其磷灰石包裹体的证据
巨型斑岩矿床的形成需要在演化的跨地壳岩浆系统中积累高达数十亿吨的挥发物(H2O、Cl和S),然后通过上部地壳岩浆室的挥发物析出集中释放到热液系统中。然而,来自同一母岩浆系统的成矿岩浆脉冲和无矿岩浆脉冲在初始挥发成分或溶出条件上是否存在差异,目前尚不清楚。这种不确定性阻碍了我们对大量挥发物如何富集和提供斑岩矿化的关键驱动因素的理解。本文研究了紫金山矿田前(109.7±0.8 Ma)、同矿(103.1±1.1 Ma)和矿后(98.1±1.1 Ma)侵入体的锆石水含量和含锆石磷灰石挥发性成分。这些数据,连同数值模拟,使我们能够说明岩浆系统的挥发演化,该岩浆系统形成了华南最大的白垩纪斑岩型铜钼矿床。虽然地球化学性质相似,但这些共源岩浆的挥发成分和演化模式却截然不同。同矿斑岩中含锆磷灰石包裹体的Cl (0.14-2.94 wt%)和F (0.04-3.37 wt%)含量变化很大,而矿前和矿后侵入体中的磷灰石的卤素变化较为有限(Cl为0.62-2.70 wt%, F为0.41-1.56 wt%)。磷灰石演化趋势的数值模拟表明,同矿岩浆具有最高的初始熔体H2O (~ 5.0 wt%)和Cl (~ 1300 ppm)含量,在最深处溶出平均聚集盐度为3.24±0.57 wt% NaCleq的流体。这些结果与锆石OH -含量和黑云母al温标一致,表明同矿斑岩具有最高的饱和压力(~ 211 MPa)。我们认为,中等Cl含量岩浆在>; 200 MPa下的流体析出优化了Cl- cu的萃取效率,促进了整个岩浆室连通流体网络的形成,有利于流体向上运移和随后的矿化。相比之下,模拟表明,前矿岩浆具有中等初始熔体H2O (~ 4.0 wt%),但Cl含量最低(~ 700 ppm),产生的盐水较少(< 3.0 wt% NaCleq),这阻碍了金属的提取。矿石后岩浆,尽管初始Cl (~ 1100 ppm)相对较高,流体盐度(3.36±1.40 wt% NaCleq)相当,但H2O(3.72±0.70 wt%)最低,并在最低压力(~ 78 MPa)下饱和,限制了Cu的提取、溶解流体量和集中流体通量。研究结果表明,同矿挥发性富集主要发生在下地壳岩浆储层内。在缺乏直接基性岩浆补给的同位素证据的情况下,我们提出来自底板基性岩浆的流体,而不是直接岩浆混合,提供了ZOF斑岩矿化所需的关键挥发性收支。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Geochimica et Cosmochimica Acta
Geochimica et Cosmochimica Acta 地学-地球化学与地球物理
CiteScore
9.60
自引率
14.00%
发文量
437
审稿时长
6 months
期刊介绍: Geochimica et Cosmochimica Acta publishes research papers in a wide range of subjects in terrestrial geochemistry, meteoritics, and planetary geochemistry. The scope of the journal includes: 1). Physical chemistry of gases, aqueous solutions, glasses, and crystalline solids 2). Igneous and metamorphic petrology 3). Chemical processes in the atmosphere, hydrosphere, biosphere, and lithosphere of the Earth 4). Organic geochemistry 5). Isotope geochemistry 6). Meteoritics and meteorite impacts 7). Lunar science; and 8). Planetary geochemistry.
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