{"title":"Magnesia-stabilized zirconia (MSZ) thermal barrier coatings by suspension plasma spraying: Coating properties and service life behavior","authors":"B.S. Constantino , Y.J. Sohn , G. Mauer","doi":"10.1016/j.jeurceramsoc.2025.117790","DOIUrl":null,"url":null,"abstract":"<div><div>Magnesia-stabilized zirconia (MSZ) coatings have low thermal conductivity and a high melting point. Currently, they are only indicated for use at lower temperatures than well-established yttria-stabilized zirconia (YSZ) coatings. This study investigated the life behavior of MSZ TBCs. The TBCs were prepared using two thermal spray technologies: atmospheric plasma spray (APS) and suspension plasma spray (SPS). The NiCoCrAlHfSi bond coat was pre-oxidized. The double-layer system, consisting of an APS intermediate layer of yttria-stabilized zirconia (YSZ) and an SPS top layer of MSZ, outperformed the single-layer MSZ APS and MSZ SPS pre-oxidized coatings. These results suggest that multi-layer coatings have the potential to improve MSZ coating performance. The influence of low-content titania doping was also investigated; however, no significant effect on the performance of the coatings was observed.</div></div>","PeriodicalId":17408,"journal":{"name":"Journal of The European Ceramic Society","volume":"46 2","pages":"Article 117790"},"PeriodicalIF":6.2000,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The European Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0955221925006119","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0
Abstract
Magnesia-stabilized zirconia (MSZ) coatings have low thermal conductivity and a high melting point. Currently, they are only indicated for use at lower temperatures than well-established yttria-stabilized zirconia (YSZ) coatings. This study investigated the life behavior of MSZ TBCs. The TBCs were prepared using two thermal spray technologies: atmospheric plasma spray (APS) and suspension plasma spray (SPS). The NiCoCrAlHfSi bond coat was pre-oxidized. The double-layer system, consisting of an APS intermediate layer of yttria-stabilized zirconia (YSZ) and an SPS top layer of MSZ, outperformed the single-layer MSZ APS and MSZ SPS pre-oxidized coatings. These results suggest that multi-layer coatings have the potential to improve MSZ coating performance. The influence of low-content titania doping was also investigated; however, no significant effect on the performance of the coatings was observed.
期刊介绍:
The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.