Properties evaluation of polyester composites with fillers for electrical sector applications

Paulo S. Neto, Jhonatan B. de Oliveira, Renata S. de O Buzatti, Venilton M.V. Ferreira, Patterson P. de Souza, Fabiano D. Chaves, Antonio S. C. Netto, Antonio M. M. S. Lameirão, Carlos A. M. Gomes, Diego C. Morgado, Marcelo B. S. Maia, Raphael F. G. Lima, Victor S. Cruz, Patrícia S. de O Patricio, Ângelo R. de Oliveira
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Abstract

Developing advanced polymeric composites is pivotal for enhancing the performance and sustainability of materials used across various industries, including the electrical sector. This study investigates isophthalic-polyester composites reinforced with clay feldspar, calcite, and glass fiber powder for their mechanical, electrical, thermal, and morphological properties. Compression tests showed that IsoFG50 (fiberglass power) exhibited the highest mechanical strength, with a 24% increase in compressive stress (140 MPa) and a 60% increase in modulus of elasticity. In contrast, IsoCF50 (clay feldspar) showed the lowest tensile strength, decreasing from 40 MPa (pure polymer) to 15 MPa. Electrical conductivity tests confirmed that all composites exhibited insulating behavior (conductivities in the range of 10− 6 Ω−1 m− 1), ensuring suitability for electrical applications. SEM (scanning electron microscopy) analysis showed that IsoFG50 had a well-distributed glass fiber network, which improved mechanical integrity, while IsoCF50 had weak matrix adhesion with visible gaps. Contact angle measurements showed that IsoCF50 and IsoFG50 had a contact angle of over 90°, confirming hydrophobicity. Flammability tests classified all reinforced composites as non-flammable, underlining their applicability in the electrical sector. These results emphasize the potential of polyester composites with mineral fillers for insulating applications, protective components, and structural elements in electrical systems. The improved mechanical properties, electrical insulation, and resistance to environmental stresses indicate that they represent a sustainable alternative to conventional materials for electrical applications. Future research should focus on optimizing filler dispersion and improving interfacial adhesion to maximize the performance of the composites.

电气领域用填料聚酯复合材料的性能评价
开发先进的聚合物复合材料对于提高包括电气行业在内的各个行业使用的材料的性能和可持续性至关重要。本研究研究了粘土长石、方解石和玻璃纤维粉增强的等眼凝树脂-聚酯复合材料的机械、电学、热学和形态性能。压缩试验表明,IsoFG50(玻璃纤维粉)具有最高的机械强度,压缩应力(140 MPa)增加24%,弹性模量增加60%。而IsoCF50(粘土长石)的抗拉强度最低,从40 MPa(纯聚合物)降至15 MPa。电导率测试证实,所有复合材料都具有绝缘性能(电导率在10−6 Ω−1 m−1范围内),确保了电气应用的适用性。SEM(扫描电镜)分析表明,IsoCF50具有分布均匀的玻璃纤维网络,提高了机械完整性,而IsoCF50的基质粘附性较弱,有明显的间隙。接触角测量表明,IsoCF50和IsoFG50的接触角大于90°,证实了其疏水性。可燃性测试将所有增强复合材料分类为不可燃,强调其在电气领域的适用性。这些结果强调了具有矿物填料的聚酯复合材料在绝缘应用、保护元件和电气系统结构元件方面的潜力。改进的机械性能、电绝缘性和对环境压力的抵抗力表明,它们代表了传统电气应用材料的可持续替代品。未来的研究应集中在优化填料分散和改善界面附着力上,以最大限度地提高复合材料的性能。
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