{"title":"Exponentially strong leakage current increase in the proton-irradiated silicon nitride","authors":"A.A. Gismatulin , V.A. Gritsenko","doi":"10.1016/j.scriptamat.2025.116968","DOIUrl":null,"url":null,"abstract":"<div><div>The charge transport in a strong electric field in proton-irradiated amorphous silicon nitride films with different irradiation doses is studied experimentally and theoretically. The leakage current increases with the increasing irradiation dose. The Frenkel model and the model of overlapping Coulomb potentials do not explain the charge transport mechanism. The charge transport mechanism in the initial Si<sub>3</sub>N<sub>4</sub> film is explained by the Makram-Ebeid and Lannoo multiphonon isolated trap ionization model. The increase in the leakage current during irradiation is quantitatively described by the phonon-assisted tunneling of electrons between neighboring traps. Such a model explains the exponentially strong leakage current scatter in non-stoichiometric SiN<em><sub>x</sub></em> films.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"270 ","pages":"Article 116968"},"PeriodicalIF":5.6000,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225004300","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The charge transport in a strong electric field in proton-irradiated amorphous silicon nitride films with different irradiation doses is studied experimentally and theoretically. The leakage current increases with the increasing irradiation dose. The Frenkel model and the model of overlapping Coulomb potentials do not explain the charge transport mechanism. The charge transport mechanism in the initial Si3N4 film is explained by the Makram-Ebeid and Lannoo multiphonon isolated trap ionization model. The increase in the leakage current during irradiation is quantitatively described by the phonon-assisted tunneling of electrons between neighboring traps. Such a model explains the exponentially strong leakage current scatter in non-stoichiometric SiNx films.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.