Structure of the Coordination Polymer Based on Zinc and R-Hexahydromandelic Acid

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Structural Chemistry Pub Date : 2025-08-29 DOI:10.1134/S0022476625080049

M. S. Zavakhina, D. G. Samsonenko, P. V. Dorovatovskii, V. A. Lazarenko

引用次数: 0

Abstract

Single crystals of chiral coordination polymer [Zn(R-Hhhm)₂] (1) are obtained in the interaction of zinc acetate and R-hexahydromandelic acid (R-H₂hhm) in a water-methanol solution. The compound has a chain structure, which is determined by single crystal X-ray diffraction with synchrotron radiation. Coordination polymer [Zn(R-Hhhm)₂] is the first example of the structurally characterized coordination compound containing hexahydromandelic acid anions.

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锌与r -六氢扁桃酸配位聚合物的结构

在水-甲醇溶液中，醋酸锌与r-六氢杨桃酸（R-H2hhm）相互作用，得到了手性配位聚合物[Zn(R-Hhhm)2](1)的单晶。该化合物具有链式结构，通过同步辐射单晶x射线衍射测定。配位聚合物[Zn(R-Hhhm)2]是结构表征的含有六氢桃酸阴离子的配位化合物的第一个例子。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Structural Chemistry 化学-无机化学与核化学

CiteScore

1.60

自引率

12.50%

发文量

142

审稿时长

8.3 months

期刊介绍： Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.