Amei Zhang , Darong Yu , Hongping Hou , Na Liao , Xueguang Zhang , Zhuang Miao , Man Li , Haixia Jing , Shen Bi , Hongliang Du , Longlong Shu
{"title":"Enhanced flexoelectricity of barium titanate ceramics by air plasma surface modification","authors":"Amei Zhang , Darong Yu , Hongping Hou , Na Liao , Xueguang Zhang , Zhuang Miao , Man Li , Haixia Jing , Shen Bi , Hongliang Du , Longlong Shu","doi":"10.1016/j.scriptamat.2025.116960","DOIUrl":null,"url":null,"abstract":"<div><div>The electromechanical coupling properties of perovskite-based ceramics, particularly their flexoelectric behavior, hold great potential for applications in sensing and actuation. In this study, we focus on improving the flexoelectric properties of these materials through interface regulation. Where the surface is modified using dielectric barrier discharge technology. The plasma-induced physical and chemical reaction introduces hydroxyl groups on the surface, enhancing the directional polarization ability of the BaTiO<sub>3</sub> crystals and ultimately improving its electrical properties. The results indicate that a 2-mins plasma modification is the most effective in enhancing the flexoelectric properties of BaTiO3. The dielectric constant at high temperatures increases by approximately 23%, and the flexoelectric coefficient at room temperature increases by about 480%. This study introduces a new approach for improving flexoelectric properties and opens up possibilities for more efficient industrial production in the future.</div></div>","PeriodicalId":423,"journal":{"name":"Scripta Materialia","volume":"270 ","pages":"Article 116960"},"PeriodicalIF":5.6000,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Scripta Materialia","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1359646225004221","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The electromechanical coupling properties of perovskite-based ceramics, particularly their flexoelectric behavior, hold great potential for applications in sensing and actuation. In this study, we focus on improving the flexoelectric properties of these materials through interface regulation. Where the surface is modified using dielectric barrier discharge technology. The plasma-induced physical and chemical reaction introduces hydroxyl groups on the surface, enhancing the directional polarization ability of the BaTiO3 crystals and ultimately improving its electrical properties. The results indicate that a 2-mins plasma modification is the most effective in enhancing the flexoelectric properties of BaTiO3. The dielectric constant at high temperatures increases by approximately 23%, and the flexoelectric coefficient at room temperature increases by about 480%. This study introduces a new approach for improving flexoelectric properties and opens up possibilities for more efficient industrial production in the future.
期刊介绍:
Scripta Materialia is a LETTERS journal of Acta Materialia, providing a forum for the rapid publication of short communications on the relationship between the structure and the properties of inorganic materials. The emphasis is on originality rather than incremental research. Short reports on the development of materials with novel or substantially improved properties are also welcomed. Emphasis is on either the functional or mechanical behavior of metals, ceramics and semiconductors at all length scales.