Optical Coupling Optimization Enables Cost-Effective Planar Silicon-Perovskite Tandem Solar Cells

IF 12
Zishuo Wang, Xianggang Chen, Xuzheng Feng, Shuyi Liu, Jixiang Tang, Yuhang Xie, Xiaoxu Sun, Shuyuan Fan, Longfei Yan, Xing Li, Molang Cai
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Abstract

Planar silicon/perovskite tandem solar cells exhibit significant advantages over textured architectures, including simplified fabrication, reduced cost, and scalability for industrial production. However, their planar configuration inherently leads to substantial optical losses. Here, we systematically analyze optical loss mechanisms in planar silicon/perovskite tandem devices and develop an optical simulation framework to address current-matching challenges between sub-cells. Through precise manipulation of hole transport layer thickness, we demonstrate synergistic optimization of parasitic absorption and reflection in the top cell. This approach yields a semi-transparent device with a short-circuit current density of 19.48 mA/cm² and a power conversion efficiency of 20.37%. An optical coupling model is established to determine optimal layer thicknesses under current-matched conditions for a tandem device. For bifacial configurations, active layer thickness and bandgap are co-optimized. Simulation results reveal that a 1.56 eV bandgap perovskite layer (800 nm) achieves 35.40% efficiency at 0.3 albedo. Cost analysis shows bifacial devices reduce the levelized cost of energy to $0.258/W at 0.3 albedo, representing a 12.8% reduction compared to single-sided Ag-coated counterparts. This study provides a comprehensive optical design strategy and cost-performance evaluation, offering critical insights for developing next-generation low-cost, high-efficiency tandem photovoltaic architectures.

Abstract Image

光学耦合优化使具有成本效益的平面硅-钙钛矿串联太阳能电池成为可能
与纹理结构相比,平面硅/钙钛矿串联太阳能电池具有显著的优势,包括简化制造、降低成本和工业生产的可扩展性。然而,它们的平面结构固有地导致了大量的光学损耗。在这里,我们系统地分析了平面硅/钙钛矿串联器件的光损耗机制,并开发了一个光学模拟框架来解决子电池之间的电流匹配挑战。通过对空穴传输层厚度的精确控制,我们证明了顶层细胞寄生吸收和反射的协同优化。这种方法产生的半透明器件的短路电流密度为19.48 mA/cm²,功率转换效率为20.37%。为了确定电流匹配条件下串联器件的最佳层厚,建立了光耦合模型。对于双面结构,有源层厚度和带隙是共同优化的。仿真结果表明,1.56 eV (800 nm)带隙钙钛矿层在0.3反照率下的效率为35.40%。成本分析显示,在反照率为0.3时,双面器件的平准化能源成本降至0.258美元/瓦,与单面镀银器件相比降低了12.8%。这项研究提供了一个全面的光学设计策略和成本性能评估,为开发下一代低成本、高效率的串联光伏架构提供了重要的见解。
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