Construction of BiOBr/Bi2WO6 S-scheme heterojunction photocatalyst for enhanced photocatalytic degradation for tetracycline removal

IF 1.5 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Lan Zhang, Zhipeng Zou, Baofei Hao, Huizhong Ma
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Abstract

In this study, Bi2WO6/BiOBr S-scheme heterojunction composites were synthesized via a one-step solvothermal method. The experimental results demonstrate that the Bi2WO6/BiOBr composites exhibit a significant redshift in the light absorption edge and a reduction in bandgap compared with that of individual Bi2WO6 and BiOBr. Meanwhile, the separation and transfer of photogenerated carriers were accelerated in Bi2WO6/BiOBr composites. In the photocatalytic degradation of tetracycline, the best composite displayed the highest photocatalytic activity, achieving a degradation efficiency of 91.3% after 60 min of light irradiation. Moreover, it maintained good stability even after four cycles. The enhancement in photocatalytic activity is primarily attributed to the formation of the S-scheme heterojunction and the strengthened interfacial interactions.

Abstract Image

BiOBr/Bi2WO6 s型异质结光催化剂的构建及其光催化降解四环素的研究
本研究采用一步溶剂热法合成了Bi2WO6/BiOBr s型异质结复合材料。实验结果表明,与单独的Bi2WO6和BiOBr相比,Bi2WO6/BiOBr复合材料具有明显的光吸收边红移和带隙减小。同时,光生载流子在Bi2WO6/BiOBr复合材料中的分离和转移速度加快。在光催化降解四环素中,效果最好的复合材料表现出最高的光催化活性,光照60 min后降解效率达到91.3%。此外,即使经过四个周期,它也保持了良好的稳定性。光催化活性的增强主要是由于s型异质结的形成和界面相互作用的增强。
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来源期刊
CiteScore
3.40
自引率
11.10%
发文量
216
审稿时长
7.5 months
期刊介绍: The Journal of the Chinese Chemical Society was founded by The Chemical Society Located in Taipei in 1954, and is the oldest general chemistry journal in Taiwan. It is strictly peer-reviewed and welcomes review articles, full papers, notes and communications written in English. The scope of the Journal of the Chinese Chemical Society covers all major areas of chemistry: organic chemistry, inorganic chemistry, analytical chemistry, biochemistry, physical chemistry, and materials science.
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