Rheo-NMR velocimetry of nanocrystalline cellulose suspensions.

IF 1.8
Maribelle A Stanley, Jayesha S Jayaratne, Sarah L Codd, Dilpreet S Bajwa, James N Wilking, Joseph D Seymour
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引用次数: 0

Abstract

The velocity data presented demonstrate the complicated flow behavior of nanocrystalline cellulose (NCC) suspensions even when standard rheometry shows only subtle effects. Rheo-nuclear magnetic resonance (NMR) velocimetry with spatial and temporal resolution indicates that NCC suspensions undergo varying flow behavior, which correlates with bulk rheology and includes wall-slip, shear banding, and yielding. Large-velocity fluctuations in a chiral nematic liquid crystal-phase suspension (5% w/v) indicate particle director orientation tumbling and flow. The results provide details of the mesoscale velocity distributions in space and time, which can be used to inform the interpretation of rheology data, as well as processing flow conditions to control NCC suspension microstructure and impact properties of composite and other materials.

纳米纤维素悬浮液的流变核磁共振测速。
流速数据显示了纳米纤维素悬浮液的复杂流动行为,即使标准流变学仅显示细微的影响。具有空间和时间分辨率的流变核磁共振(NMR)测速表明,NCC悬浮液具有不同的流动行为,这些流动行为与体流变有关,包括壁滑移、剪切带和屈服。手性向列型液晶相悬浮液(5% w/v)的大流速波动表明颗粒定向翻滚和流动。研究结果提供了中尺度速度分布在空间和时间上的详细信息,可用于解释流变数据,以及控制复合材料和其他材料的NCC悬浮液微观结构和冲击性能的加工流动条件。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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