Mineralogical and Chemical Mapping of Martian Meteorite SaU 008 Using Deep UV Raman and Fluorescence Spectroscopy on Earth and Mars

Abstract

The NASA Mars 2020 mission Perseverance rover carries a piece of Martian meteorite Sayh al Uhaymir (SaU) 008 as part of the calibration payload for the SHERLOC science instrument. We report SHERLOC observations of the SaU 008 flight piece over the first 1,000 sols of the mission and compare them to measurements done prior to launch, showing consistent detection of the same deep-ultraviolet (DUV) Raman and fluorescence signatures in the same locations. Co-located X-ray fluorescence (XRF) and DUV mapping of a reference SaU 008 piece on Earth confirm that the meteorite is comprised of an igneous mineral matrix consistent with shergottite, rich in olivine, maskelynite, and Fe-Mg pyroxenes detectable by SHERLOC. Terrestrial weathering features consist of fractures and vugs filled with Ca-carbonate. Fluorescence mapping reveals two major signatures: (a) broad-spectrum fluorescence present throughout the igneous matrix but strongest in weathering features, attributed to organic material, and (b) narrow-band 340 nm fluorescence spatially associated with ∼48 ppm cerium in <100 μm Ca-phosphate grains. Raman revealed organic material in both the igneous matrix and terrestrial carbonate in the form of macromolecular carbon (MMC) with defect and graphitic bands at ∼1,380 and ∼1,600 cm⁻¹ respectively. Raman band parameters suggest that MMC associated with terrestrial weathering is less thermally mature, most likely the result of chemical alteration after landing on Earth. This study serves as a demonstration of SHERLOC's capabilities when supported by co-located XRF data from PIXL and suggests that SHERLOC can detect Ce in phosphate minerals at concentrations as low as 4 ppm.