Extraction of Pure Plastic Resins From PCR Plastic Waste by Solvent-Targeted Recovery and Precipitation (STRAP)

Zhuo Xu, Fei Long, Zach Wagner, Charles Granger, Euncheol Ra, Shiying Cai, George W. Huber, Ezra Bar-Ziv
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Abstract

We have been developing a solvent-based plastic recycling technology called STRAP. The technology is based on dissolving a targeted plastic resin in a specific solvent that does not dissolve other resins. We have demonstrated STRAP in thousands of bench scale experiments for a large variety of wastes. Recently we have demonstrated the technology for PCR, using mixed plastic wastes (MPWs), from a wet Material Recovery Facility (MRF). The process includes (1) infrared (IR) characterization to determine the plastic composition for accurate selection of the solvent to be used for the extraction of the pure resins. (2) Shredding to the right size and aspect ratio required for flowable and fast dissolvable process. (3) Mixing the MPW in the first solvent to dissolve the first resin. (4) Filtration of the solution plastic blend, to separate the nondissolved plastic from the solution. (5) Further filtration of the solution to remove micron-sized particle of pigments and fibers. (6) Cooling for precipitation. (7) Filtration of pure resins. (8) Drying of a pure resin. (9) Extrusion of the resin to pellets. (10) Generating films or other products from the pure resin. Steps 1–10 can be considered as one-cycle that extracted the first resin. (11) A second resin can be extracted with a respective solvent from the plastic that did not dissolve in the first cycle and following steps 1–10 described above. The process also includes characterization of interim and final products. The effort includes building a pilot system at 25 kg/h throughput. We will present specific results for various PCR.

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溶剂定向回收沉淀法(STRAP)从PCR废塑料中提取纯塑料树脂
我们一直在开发一种名为STRAP的溶剂型塑料回收技术。该技术是基于将目标塑料树脂溶解在特定溶剂中,而不溶解其他树脂。我们已经在成千上万的各种废物的实验中展示了STRAP。最近,我们展示了聚合酶链反应技术,使用来自湿材料回收设施(MRF)的混合塑料废物(mpw)。该过程包括(1)红外(IR)表征,以确定塑料成分,以准确选择用于提取纯树脂的溶剂。(2)按流动和快速溶解工艺所需的合适尺寸和宽高比粉碎。(3)将MPW与第一种溶剂混合,使第一种树脂溶解。(4)对溶液塑料混合物进行过滤,将未溶解的塑料从溶液中分离出来。(5)进一步过滤溶液,去除微米级的颜料和纤维颗粒。(6)冷却降水。(7)纯树脂过滤。(8)干燥纯树脂。(9)树脂挤压成球团。(10)由纯树脂生成薄膜或其他产品。步骤1-10可以认为是提取第一种树脂的一个周期。(11)第二种树脂可以用相应的溶剂从第一个循环中未溶解的塑料中提取,并遵循上述步骤1-10。该过程还包括中间产品和最终产品的表征。这项工作包括建立一个25公斤/小时吞吐量的试点系统。我们将介绍各种PCR的具体结果。
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CiteScore
4.50
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