Recent advances in the chemistry of 1,4-oxaselen(anes) ines, Benzo[b][1,4]oxaselenines and phenoxaselenines and their analogues

IF 2.1 3区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Organometallic Chemistry Pub Date : 2025-07-08 DOI:10.1016/j.jorganchem.2025.123763

Mohamed H. Helal , Rasha Jame , Mohamed A. Salem , Aisha R. Al-Marhabi , Moustafa A. Gouda

引用次数: 0

Abstract

1,4-Oxaselenanes, six-membered heterocyclic compounds containing one oxygen and one selenium atom, are relatively underexplored molecule in organic and medicinal chemistry. Preliminary studies suggest potential biological activities, including anticancer properties, attributed to selenium’s role in biochemical redox processes.

1,4-Oxaselenanes are of particular interest in materials science due to their optical and electronic properties. The synthesis of 1,4-oxaselen(anes) ines, benzo[b][1,4]oxaselenine and phenoxaselenine, along with their derivatives, can be accomplished using various methods. These include (i) Selenation reactions, (ii) photolysis of selenadiazoles in furan, (iii) cyclization reactions of selenocyanates and (2-aryloxyphenyl)boronic acids in addition to other strategies.

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1,4- oxaseline、苯并[b][1,4] oxaseline和苯oxaseline及其类似物的化学研究进展

1,4-草烯烷是一种含一个氧和一个硒原子的六元杂环化合物，是有机化学和药物化学中研究相对较少的分子。初步研究表明潜在的生物活性，包括抗癌特性，归因于硒在生化氧化还原过程中的作用。由于其光学和电子性质，1,4-草二烯烷在材料科学中引起了特别的兴趣。1,4- oxaseline (anes)，苯并[b][1,4] oxaseline和苯oxaseline及其衍生物的合成可以通过各种方法完成。这些包括(i)硒化反应，（ii）硒二唑在呋喃中的光解反应，（iii）硒氰酸酯和（2-芳基苯基）硼酸的环化反应以及其他策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Organometallic Chemistry 化学-无机化学与核化学

CiteScore

4.40

自引率

8.70%

发文量

221

审稿时长

36 days

期刊介绍： The Journal of Organometallic Chemistry targets original papers dealing with theoretical aspects, structural chemistry, synthesis, physical and chemical properties (including reaction mechanisms), and practical applications of organometallic compounds. Organometallic compounds are defined as compounds that contain metal - carbon bonds. The term metal includes all alkali and alkaline earth metals, all transition metals and the lanthanides and actinides in the Periodic Table. Metalloids including the elements in Group 13 and the heavier members of the Groups 14 - 16 are also included. The term chemistry includes syntheses, characterizations and reaction chemistry of all such compounds. Research reports based on use of organometallic complexes in bioorganometallic chemistry, medicine, material sciences, homogeneous catalysis and energy conversion are also welcome. The scope of the journal has been enlarged to encompass important research on organometallic complexes in bioorganometallic chemistry and material sciences, and of heavier main group elements in organometallic chemistry. The journal also publishes review articles, short communications and notes.