The effective role of by – product of PANI/V2O5 in improving the electrolytic performance of p – toluene sulphonic acid

Aranganathan Viswanathan, Megha Naik, Theertha P. Ramesh, Adka Nityananda Shetty
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Abstract

The use of liquid by-product obtained after the synthesis of electrode material as base fluid for the preparation of aqueous electrolytes instead of distilled water is beneficial in improving the electrolytic performance of aqueous electrolytes. The p – toluene sulphonic acid (PTSA) as electrolyte exhibited superior performance when prepared using the by-product obtained after the synthesis of PANI/V2O5 nanocomposite (PV) as a base fluid (PTSA+SL) to the electrolyte prepared using distilled water (PTSA). The PV exhibited 21.30 % higher energy storage in the presence (ITP) of PTSA+SL compared with that attained ITP of PTSA. The capacity (Q) and maximum energy stored (Emax) obtained ITP of PTSA are 1.13 C and 0.18 W h at 5 mV s1. The Q and Emax achieved ITP of PTSA+SL are 1.38 C and 0.23 W h at 5 mV s1. The utilization of by-products of the synthesis of electrode material back into the energy storage process brings this approach in to the umbrella of green energy storage processes. In addition, this approach personifies the concept of “waste to wealth” approach to work towards the sustainability in energy storage.
PANI/V2O5副产物对改善对甲苯磺酸电解性能的有效作用
用电极材料合成后得到的液体副产物代替蒸馏水作为基液制备水性电解质,有利于提高水性电解质的电解性能。将PANI/V2O5纳米复合材料(PV)合成后的副产物(PTSA+SL)与蒸馏水(PTSA)制备的电解液(PTSA)作为电解液制备的对甲苯磺酸(PTSA)表现出优异的性能。在PTSA+SL存在的情况下,PV的储能比达到PTSA的ITP时高出21.30 %。在5 mV s1下,PTSA的容量(Q)和最大储能(Emax)分别为1.13 C和0.18 W h。在5 mV s1下,PTSA+SL的Q值和Emax值分别为1.38 C和0.23 W h。将电极材料合成的副产品利用到储能过程中,将这种方法纳入了绿色储能过程的范畴。此外,这种方法体现了“废物转化财富”的概念,以实现能源储存的可持续性。
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