Nondestructive Identification of Paper Based on Relative Formation Time Using Three-Dimensional Fluorescence Spectroscopy Combined With Supervised Learning

IF 2.3 4区 化学 Q1 SOCIAL WORK
Xiaohong Chen, Yuhuan He, Lan Cui, Hongda Li, Xiaojing Wu
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引用次数: 0

Abstract

In order to achieve nondestructive analysis and identification of the relative formation time of paper evidence and to solve the difficulties in document authenticity identification in the field of forensic science, this study selected three-dimensional fluorescence spectroscopy data of paper evidence of the same brand and model collected in the same storage environment within the last decade (2012–2023). After preprocessing steps like eliminating scattering, smoothing noise and principal component analysis (PCA), machine learning algorithms such as K-nearest neighbor (KNN) and linear discriminant analysis (LDA) were employed to classify and predict specific feature bands. The accuracy of KNN and LDA was 94.5% and 98.9%, respectively. Furthermore, relative formation time prediction was conducted for paper samples by LDA in the sample library, achieving an accuracy rate of 98.0%. Finally, the established model was successfully applied to analyze an actual case involving suspected “forged official documents.” It accurately determined the relative formation time of the forged paper, and the analysis results were consistent with the suspect's confession.

基于相对形成时间的三维荧光光谱与监督学习相结合的纸张无损识别
为了实现对纸质证据相对形成时间的无损分析与鉴定,解决法医学领域文书真实性鉴定的难题,本研究选取了近十年(2012-2023年)在同一存储环境下采集的同品牌、同型号纸质证据的三维荧光光谱数据。在消除散射、平滑噪声和主成分分析(PCA)等预处理步骤之后,采用k近邻(KNN)和线性判别分析(LDA)等机器学习算法对特定特征波段进行分类和预测。KNN和LDA的准确率分别为94.5%和98.9%。利用LDA对样本库中的纸质样本进行相对形成时间预测,准确率达到98.0%。最后,将所建立的模型成功地应用于一起涉嫌“伪造公文”的实际案例分析。准确确定了伪造纸的相对形成时间,分析结果与犯罪嫌疑人的供词一致。
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来源期刊
Journal of Chemometrics
Journal of Chemometrics 化学-分析化学
CiteScore
5.20
自引率
8.30%
发文量
78
审稿时长
2 months
期刊介绍: The Journal of Chemometrics is devoted to the rapid publication of original scientific papers, reviews and short communications on fundamental and applied aspects of chemometrics. It also provides a forum for the exchange of information on meetings and other news relevant to the growing community of scientists who are interested in chemometrics and its applications. Short, critical review papers are a particularly important feature of the journal, in view of the multidisciplinary readership at which it is aimed.
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