Di-aqua-bis-(dl-α-lipoato-κ² O,O')manganese(II).

IUCrData Pub Date : 2025-06-27 eCollection Date: 2025-06-01 DOI:10.1107/S2414314625005656

Farkhod Raxmatovich Jumabaev, Avez Tuymuradovich Sharipov, Vazirakhon Khasanxoja Kizi Mannopova, Odil Irgashevich Choriyev, Jamshid Mengnorovich Ashurov

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引用次数: 0

Abstract

The manganese(II) coordination compound, [Mn(C₈H₁₃S₂O₂)₂(H₂O)₂], with two bidentate α-lipoate ligands and two coordinating water mol-ecules, has been structurally characterized. The cantral Mn^II atom lies on a crystallographic twofold rotation axis and adopts a distorted octa-hedral coordination environment, with carboxyl-ate groups chelating the metal in a κ² O,O'-binding mode. One of the sulfur atoms within the 1,2-di-thiol-ane ring exhibits positional disorder over two sites, with refined occupancies of 0.92 and 0.08. The complex is isostructural with previously reported Zn^II and Cd^II analogues, both of which also display positional disorder in the 1,2-di-thiol-ane ring. The mol-ecules are linked via inter-molecular O-H⋯O and C-H⋯S hydrogen bonds into a di-periodic supramolecular framework parallel to (100).

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Di-aqua-bis - dl -α-lipoato -κ2或奥),锰(II)。

对具有两个双齿α-脂酸配体和两个配位水分子的锰（II）配位化合物[Mn(C8H13S2O2)2(H2O)2]进行了结构表征。中心的MnII原子位于晶体双旋转轴上，采用畸变八面体配位环境，羧酸基以κ 2o，O'键模式与金属螯合。1,2-二硫醇环内的一个硫原子在两个位置上表现出位置紊乱，其精确占有率分别为0.92和0.08。该配合物与先前报道的ZnII和CdII类似物是同构的，两者在1,2-二硫醇环上也表现出位置紊乱。分子通过分子间的O- h⋯O和C-H⋯S氢键连接成平行于（100）的双周期超分子框架。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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IUCrData

CiteScore

0.30

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0.00%

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