Firudin I Guseinov, Aida I Samigullina, Tuncer Hökelek, Sahil Z Hamidov, Jamal Lasri, Khudayar I Hasanov, Tahir A Javadzade, Alebel N Belay
{"title":"1-[(2-Bromo-phen-yl)di-phenyl-meth-yl]-3-(tri-fluorometh-yl)-1<i>H</i>-pyrazole-1-(tri-phenyl-meth-yl)-3-(tri-fluoro-meth-yl)-1<i>H</i>-pyrazole (0.638:0.362).","authors":"Firudin I Guseinov, Aida I Samigullina, Tuncer Hökelek, Sahil Z Hamidov, Jamal Lasri, Khudayar I Hasanov, Tahir A Javadzade, Alebel N Belay","doi":"10.1107/S2414314625004663","DOIUrl":null,"url":null,"abstract":"<p><p>In the title compound, 0.638C<sub>23</sub>H<sub>16</sub>BrF<sub>3</sub>N<sub>2</sub>·0.362C<sub>23</sub>H<sub>17</sub>F<sub>3</sub>N<sub>2</sub>, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers, enclosing <i>R</i> <sup>2</sup> <sub>2</sub>(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) inter-actions.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 6","pages":"x250466"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12230598/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625004663","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/6/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the mol-ecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) inter-actions.
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