Enhancing combustion performance of composite propellants through chemical modification to bond nano-aluminum powder and RDX building blocks for energy release coupling
Hongxia Zhang , Fei Xiao , Chongwei An , Chen Chong , Yaozhong Ran , Yongli Zhang , Ying Li , Jiawang Shuang , Jiaru Zhang
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引用次数: 0
Abstract
Due to the difficulty in establishing organic functional groups on the surface of aluminum powder, the effective combination of aluminum powder with other oxidizing particles is inhibited, thereby limiting its energy characteristics. By introducing effective functional groups on the aluminum powder surface that can form chemical bonds, it is possible to establish links between particles and achieve three-dimensional growth of nano-aluminum powder on various oxidizer particle surfaces. In this study, we propose the creation of two building blocks: nano-aluminum (nAl) modified with 3-mercaptopropyltrimethoxysilane (MPTS) and 1,3,5-trinitro-1,3,5-triazine (RDX) modified with tannic acid (TA). Through the chemical bonding of these two building blocks, three-dimensional growth of nano-aluminum powder on the RDX surface was achieved, resulting in the preparation of RDX@Al. The results demonstrate that RDX@Al effectively reduces the activation energy of RDX, showcasing the energy coupling and synergy between RDX and nAl. Adding RDX@Al to composite propellants significantly improves the combustion performance of the propellants. Due to the shortened mass and heat transfer distances between RDX and nAl, the combustion rate of the propellant increased by 38 %, and the combustion intensity was also enhanced. Additionally, the size of the condensed phase combustion products from the propellant was reduced by 59.8 %. This work provides new insights into the design of composite energetic materials and the elucidation of the combustion mechanisms of composite solid propellants.
期刊介绍:
The mission of the journal is to publish high quality work from experimental, theoretical, and computational investigations on the fundamentals of combustion phenomena and closely allied matters. While submissions in all pertinent areas are welcomed, past and recent focus of the journal has been on:
Development and validation of reaction kinetics, reduction of reaction mechanisms and modeling of combustion systems, including:
Conventional, alternative and surrogate fuels;
Pollutants;
Particulate and aerosol formation and abatement;
Heterogeneous processes.
Experimental, theoretical, and computational studies of laminar and turbulent combustion phenomena, including:
Premixed and non-premixed flames;
Ignition and extinction phenomena;
Flame propagation;
Flame structure;
Instabilities and swirl;
Flame spread;
Multi-phase reactants.
Advances in diagnostic and computational methods in combustion, including:
Measurement and simulation of scalar and vector properties;
Novel techniques;
State-of-the art applications.
Fundamental investigations of combustion technologies and systems, including:
Internal combustion engines;
Gas turbines;
Small- and large-scale stationary combustion and power generation;
Catalytic combustion;
Combustion synthesis;
Combustion under extreme conditions;
New concepts.