Visual sensing Ni2+ in real samples with test paper based on a new dinuclear terbium complex†

IF 2.6 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

CrystEngComm Pub Date : 2025-05-21 DOI:10.1039/D5CE00117J

Ziyan Cai, Ping Li, Xiaobo Yu, Lin Lai, Cilin Yu, Yuan Hu, Xiaolei Gao and Chenghui Zeng

{"title":"Visual sensing Ni2+ in real samples with test paper based on a new dinuclear terbium complex†","authors":"Ziyan Cai, Ping Li, Xiaobo Yu, Lin Lai, Cilin Yu, Yuan Hu, Xiaolei Gao and Chenghui Zeng","doi":"10.1039/D5CE00117J","DOIUrl":null,"url":null,"abstract":"Nickel (Ni) is an essential metal element widely used in industrial production and daily life; however, long-term human exposure to nickel may lead to skin allergies, damage to genetic material, and even the possible induction of cancer. Therefore, the development of an accurate, rapid, and convenient method for detecting Ni2+ is of importance. In this work, rare earth dinuclear complex Tb-TFBA is designed and its precise structure is analyzed by single crystal analysis. Experimental results show that Tb-TFBA possesses strong anti-interference capabilities, short response time (20 s), and an extremely low detection limit (LOD = 0.1 nM); the LOD is significantly lower than the minimum detection value of the national safety standards for drinking water (20 nM, GB 5749-2022). Furthermore, a portable sensing device of test paper is developed based on Tb-TFBA. The device achieves specific visual detection of Ni2+ in real samples, which is portable and easy to use in daily life.","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 25","pages":" 4304-4311"},"PeriodicalIF":2.6000,"publicationDate":"2025-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00117j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Nickel (Ni) is an essential metal element widely used in industrial production and daily life; however, long-term human exposure to nickel may lead to skin allergies, damage to genetic material, and even the possible induction of cancer. Therefore, the development of an accurate, rapid, and convenient method for detecting Ni²⁺ is of importance. In this work, rare earth dinuclear complex Tb-TFBA is designed and its precise structure is analyzed by single crystal analysis. Experimental results show that Tb-TFBA possesses strong anti-interference capabilities, short response time (20 s), and an extremely low detection limit (LOD = 0.1 nM); the LOD is significantly lower than the minimum detection value of the national safety standards for drinking water (20 nM, GB 5749-2022). Furthermore, a portable sensing device of test paper is developed based on Tb-TFBA. The device achieves specific visual detection of Ni²⁺ in real samples, which is portable and easy to use in daily life.

Abstract Image

查看原文本刊更多论文

基于新型双核铽配合物†的试纸视觉检测实际样品中的Ni2+

镍（Ni）是一种广泛应用于工业生产和日常生活的重要金属元素；然而，人类长期接触镍可能导致皮肤过敏，损害遗传物质，甚至可能诱发癌症。因此，开发一种准确、快速、方便的Ni2+检测方法具有重要意义。本文设计了稀土双核配合物Tb-TFBA，并通过单晶分析对其精确结构进行了分析。实验结果表明，Tb-TFBA抗干扰能力强，响应时间短（20 s），检出限极低（LOD = 0.1 nM）；LOD明显低于国家饮用水安全标准（20 nM, GB 5749-2022）的最低检测值。在此基础上，研制了一种基于Tb-TFBA的便携式试纸传感装置。该装置实现了对真实样品中Ni2+的特异性视觉检测，便携，便于日常生活使用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊