Magnetic ground state of the new perovskite variant Ba3CoSn2O9

IF 2.5 3区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

Journal of Magnetism and Magnetic Materials Pub Date : 2025-06-16 DOI:10.1016/j.jmmm.2025.173241

Santanu De , Supratik Mukherjee , Rahul Singh , S. Karmakar , Shipra Das , U.K. Goutam , R. Rawat , G. Vaitheeswaran , P.N. Santhosh

{"title":"Magnetic ground state of the new perovskite variant Ba3CoSn2O9","authors":"Santanu De , Supratik Mukherjee , Rahul Singh , S. Karmakar , Shipra Das , U.K. Goutam , R. Rawat , G. Vaitheeswaran , P.N. Santhosh","doi":"10.1016/j.jmmm.2025.173241","DOIUrl":null,"url":null,"abstract":"<div><div>Novel materials are of great interest due to the realization of many exotic states of matter. One of these systems, Ba<sub>3</sub>CoSn<sub>2</sub>O<sub>9</sub>, belonging to perovskite variants has been synthesized followed by the magnetic ground state study. Unlike 6H-perovskites, this system is crystallized in face-centred cubic (FCC) structure under the space group, <em>Fm3̄m</em>. The magnetic cobalts are in the spin half state at octahedral sites in this A <figure><img></figure> ... stacked square lattice comprising triangular sub-lattices (TL). Moreover, the magnetic sites are partially occupied by non-magnetic tin that removes the frustrating nature of 1/2 predominantly antiferromagnetic moments in this TL system. Remaining moments in the same TL lattice get ordered antiferromagnetically at T<span><math><msub><mrow></mrow><mrow><mi>N</mi></mrow></msub></math></span> = 40 K resulting in a partially disordered antiferromagnetic state in this FCC crystal-lattice.</div></div>","PeriodicalId":366,"journal":{"name":"Journal of Magnetism and Magnetic Materials","volume":"629 ","pages":"Article 173241"},"PeriodicalIF":2.5000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnetism and Magnetic Materials","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304885325004731","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Novel materials are of great interest due to the realization of many exotic states of matter. One of these systems, Ba₃CoSn₂O₉, belonging to perovskite variants has been synthesized followed by the magnetic ground state study. Unlike 6H-perovskites, this system is crystallized in face-centred cubic (FCC) structure under the space group, Fm3̄m. The magnetic cobalts are in the spin half state at octahedral sites in this A

... stacked square lattice comprising triangular sub-lattices (TL). Moreover, the magnetic sites are partially occupied by non-magnetic tin that removes the frustrating nature of 1/2 predominantly antiferromagnetic moments in this TL system. Remaining moments in the same TL lattice get ordered antiferromagnetically at T

_{N}

= 40 K resulting in a partially disordered antiferromagnetic state in this FCC crystal-lattice.

查看原文本刊更多论文

新钙钛矿变体Ba3CoSn2O9的磁基态

由于实现了许多奇异的物质状态，新型材料引起了人们的极大兴趣。合成了其中一种钙钛矿变体体系Ba3CoSn2O9，并对其进行了磁基态研究。与6h钙钛矿不同，该体系在空间群Fm3 * m下以面心立方（FCC）结构结晶。磁性钴在八面体位置处于自旋半态。由三角形子晶格（TL）组成的堆叠方形晶格。此外，磁性位点部分被非磁性锡占据，从而消除了该TL体系中1/2主要反铁磁矩的令人沮丧的性质。在TN = 40k时，同一TL晶格中的剩余矩具有有序的反铁磁性，导致FCC晶格具有部分无序的反铁磁性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Magnetism and Magnetic Materials 物理-材料科学：综合

CiteScore

5.30

自引率

11.10%

发文量

1149

审稿时长

59 days

期刊介绍： The Journal of Magnetism and Magnetic Materials provides an important forum for the disclosure and discussion of original contributions covering the whole spectrum of topics, from basic magnetism to the technology and applications of magnetic materials. The journal encourages greater interaction between the basic and applied sub-disciplines of magnetism with comprehensive review articles, in addition to full-length contributions. In addition, other categories of contributions are welcome, including Critical Focused issues, Current Perspectives and Outreach to the General Public. Main Categories: Full-length articles: Technically original research documents that report results of value to the communities that comprise the journal audience. The link between chemical, structural and microstructural properties on the one hand and magnetic properties on the other hand are encouraged. In addition to general topics covering all areas of magnetism and magnetic materials, the full-length articles also include three sub-sections, focusing on Nanomagnetism, Spintronics and Applications. The sub-section on Nanomagnetism contains articles on magnetic nanoparticles, nanowires, thin films, 2D materials and other nanoscale magnetic materials and their applications. The sub-section on Spintronics contains articles on magnetoresistance, magnetoimpedance, magneto-optical phenomena, Micro-Electro-Mechanical Systems (MEMS), and other topics related to spin current control and magneto-transport phenomena. The sub-section on Applications display papers that focus on applications of magnetic materials. The applications need to show a connection to magnetism. Review articles: Review articles organize, clarify, and summarize existing major works in the areas covered by the Journal and provide comprehensive citations to the full spectrum of relevant literature.