Bis[5-(anthracen-9-ylmethyl)-1,5,9-triazacyclododecan-1-ium] tetrachloridozincate

IUCrData Pub Date : 2025-05-01 DOI:10.1107/S2414314625003566

Yoshimi Ichimaru , Koichi Kato , Wanchun Jin , Masaaki Kurihara , Hiromasa Kurosaki

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Abstract

The structure of the title salt comprising two monoprotonated polyamine ligands and one tetrachlorozincate(II) anion was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitrogen atoms engaged in intramolecular hydrogen bonding with other nitrogen atoms within the macrocyclic ring.

A crystalline salt comprising two monoprotonated polyamine ligands and one tetrachlorozincate(II) anion was prepared, (C₂₄H₃₂N₃)₂[ZnCl₄], and its crystal structure was analyzed and compared with those of structurally related compounds bearing different macrocyclic frameworks and pendant arms. The protonated nitrogen atoms engaged in intramolecular hydrogen bonding with other nitrogen atoms within the macrocyclic ring. In the crystal, the pendant anthracene groups participated in intermolecular π–π and C—H⋯π interactions, contributing to crystal cohesion.

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国际清算银行[5 - (anthracen-9-ylmeth-yl) 1、5、9-tri-aza-cyclododecan-1-ium] tetra-chlorido-zincate。

制备了一种由两个单质子化多胺配体和一个四氯锌酸盐（II）阴离子组成的结晶盐（C24H32N3）2[ZnCl4]，并对其晶体结构进行了分析，并与具有不同大环框架和垂臂的结构相关化合物进行了比较。质子化的氮原子在分子内与大环内的其他氮原子形成氢键。在晶体中，悬垂的蒽基团参与分子间π-π和C-H⋯π的相互作用，有助于晶体的内聚。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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