Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-di­yl)]bis­(2-methyl­sulfanyl-1H-benzo[d]imidazole)

IF 0.5 Q4 CRYSTALLOGRAPHY
Ahmed Moussaif , Lhoussaine El Ghayati , Camille Kalonji Mubengayi , Abdulsalam Alsubari , El Mokhtar Essassi , Joel T. Mague , Youssef Ramli
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引用次数: 0

Abstract

In the title compound, the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetra­molecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) inter­actions and are linked by C—H⋯π(ring) and π-stacking inter­actions.
The asymmetric unit of the title compound, C20H22N4OS2, consists of two independent mol­ecules, one of which is disordered. In each mol­ecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetra­molecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) inter­actions and are linked by C—H⋯π(ring) and π-stacking inter­actions.
1,1′-[氧双(乙烷-2,1-二基)]双-(2-甲基磺胺基- 1h -苯并咪唑)的合成、晶体结构和Hirshfeld表面分析。
标题化合物C20H22N4OS2的不对称单元由两个独立的分子组成,其中一个是无序的。在每个分子中,末端苯并咪唑基团的平均平面彼此倾斜约68°。在晶体中,四分子链由C-H⋯N氢键和C-H⋯π(环)相互作用产生,并由C-H⋯π(环)和π-堆叠相互作用连接。
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来源期刊
CiteScore
1.90
自引率
0.00%
发文量
351
审稿时长
3 weeks
期刊介绍: Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
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