Ahmed Moussaif , Lhoussaine El Ghayati , Camille Kalonji Mubengayi , Abdulsalam Alsubari , El Mokhtar Essassi , Joel T. Mague , Youssef Ramli
{"title":"Synthesis, crystal structure and Hirshfeld surface analysis of 1,1′-[oxybis(ethane-2,1-diyl)]bis(2-methylsulfanyl-1H-benzo[d]imidazole)","authors":"Ahmed Moussaif , Lhoussaine El Ghayati , Camille Kalonji Mubengayi , Abdulsalam Alsubari , El Mokhtar Essassi , Joel T. Mague , Youssef Ramli","doi":"10.1107/S2056989025003809","DOIUrl":null,"url":null,"abstract":"<div><div>In the title compound, the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.</div></div><div><div>The asymmetric unit of the title compound, C<sub>20</sub>H<sub>22</sub>N<sub>4</sub>OS<sub>2</sub>, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.</div></div>","PeriodicalId":7367,"journal":{"name":"Acta Crystallographica Section E: Crystallographic Communications","volume":"81 6","pages":"Pages 464-468"},"PeriodicalIF":0.5000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta Crystallographica Section E: Crystallographic Communications","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S205698902500101X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CRYSTALLOGRAPHY","Score":null,"Total":0}
引用次数: 0
Abstract
In the title compound, the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.
The asymmetric unit of the title compound, C20H22N4OS2, consists of two independent molecules, one of which is disordered. In each molecule, the mean planes of the terminal benzimidazole moieties are inclined to one another by about 68°. In the crystal, tetramolecular strands are generated by C—H⋯N hydrogen bonds and C—H⋯π(ring) interactions and are linked by C—H⋯π(ring) and π-stacking interactions.
期刊介绍:
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.