Crystal structure and Hirshfeld surface analysis of (E)-2-cyano-N′-(3,4,5-tri­meth­oxy­benzyl­idene)acetohydrazide

IF 0.6 Q4 CRYSTALLOGRAPHY
Subramani Uma Maheswari , Srinivasan Senthilkumar , Sivashanmugam Selvanayagam
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引用次数: 0

Abstract

In the title compound, the crystal packing features strong N—H⋯O hydrogen bonds, which form C(4) chain-motifs.
In the title compound, C13H15N3O4, the 2-cyano-N′-methyl­ideneacetohydrazide moiety and the trimeth­oxy phenol ring form a dihedral angle of 13.8 (1)°. Inter­molecular N—H⋯O and C—H⋯O hydrogen bonds are observed. The inter­molecular inter­actions were qu­anti­fied and analysed using Hirshfeld surface analysis, revealing that H⋯H inter­actions contribute most to the crystal packing (38.3%).
(E)-2-氰- n '-(3,4,5-三甲基-氧基苯二胺)乙酰肼的晶体结构和Hirshfeld表面分析。
在标题化合物C13H15N3O4中,2-氰- n′-甲基-异乙酰肼部分与三甲基-氧酚环形成13.8(1)°的二面角。观察到分子间的N-H⋯O和C-H⋯O氢键。分子间相互作用被quantified并使用Hirshfeld表面分析进行分析,揭示了H⋯H相互作用对晶体堆积的贡献最大(38.3%)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
1.90
自引率
0.00%
发文量
351
审稿时长
3 weeks
期刊介绍: Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.
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