Non-C1 Synthon Role of CO2: Promoting Divergent Electrochemical Defluorination

IF 5 1区化学 Q1 CHEMISTRY, ORGANIC

Organic Letters Pub Date : 2025-06-05 DOI:10.1021/acs.orglett.5c01723

Zixuan Zhang, Jie Liu, Zhanshuo Zhang, Guiming Liu, Yuan-Ye Jiang, Yulei Zhao

引用次数: 0

Abstract

Here, an unpresented non-C1 synthon function of CO₂ is reported to facilitate electrochemical defluorination. The introduction of CO₂ modulates the electron distribution of the radical anion intermediate generated through one-electron reduction, thereby weakening the reduction potential and facilitating reduction and defluorination. CO₂ is released subsequently via spontaneous decarboxylation to complete its promotion role. The presented results shed light on a distinctive utilization of CO₂, which may stimulate interest in developing non-C1 synthon functions of CO₂.

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CO2的非c1合成作用：促进发散型电化学除氟

在这里，一个未呈现的CO2的非c1合成词功能被报道为促进电化学除氟。CO2的引入调节了单电子还原生成的自由基阴离子中间体的电子分布，从而削弱了还原电位，有利于还原除氟。随后，二氧化碳通过自发脱羧释放，完成其促进作用。提出的结果揭示了二氧化碳的独特利用，这可能会激发人们对开发二氧化碳的非c1合成功能的兴趣。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Organic Letters 化学-有机化学

CiteScore

9.30

自引率

11.50%

发文量

1607

审稿时长

1.5 months

期刊介绍： Organic Letters invites original reports of fundamental research in all branches of the theory and practice of organic, physical organic, organometallic,medicinal, and bioorganic chemistry. Organic Letters provides rapid disclosure of the key elements of significant studies that are of interest to a large portion of the organic community. In selecting manuscripts for publication, the Editors place emphasis on the originality, quality and wide interest of the work. Authors should provide enough background information to place the new disclosure in context and to justify the rapid publication format. Back-to-back Letters will be considered. Full details should be reserved for an Article, which should appear in due course.