{"title":"Crystal structures of sandwich-type potassium cation complexes formed from benzo-15-crown-5-based ligand containing a chloromaleimide moiety†","authors":"Yuto Hirayama, Akitaka Ito and Rika Ochi","doi":"10.1039/D5CE00252D","DOIUrl":null,"url":null,"abstract":"<p >We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an <em>N</em>-phenylchloromaleimide moiety. Two geometrically different potassium cation (K<small><sup>+</sup></small>) complexes with a B15C5/K<small><sup>+</sup></small>/B15C5 sandwich structure were prepared and characterised <em>via</em> single-crystal X-ray diffraction.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 20","pages":" 3214-3218"},"PeriodicalIF":2.6000,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00252d","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
We developed a novel benzo-15-crown-5 (B15C5)-based organic ligand containing an N-phenylchloromaleimide moiety. Two geometrically different potassium cation (K+) complexes with a B15C5/K+/B15C5 sandwich structure were prepared and characterised via single-crystal X-ray diffraction.