{"title":"Discrete Paleoproterozoic and Cretaceous mineralization events at the Liyuan gold deposit, central North China Craton","authors":"Ying Ma, Shao-Yong Jiang","doi":"10.1016/j.precamres.2025.107812","DOIUrl":null,"url":null,"abstract":"<div><div>Accurate dating of Precambrian gold deposits is challenging due to the lack of suitable mineral chronometers. The North China Craton (NCC) is recognized as one of the world’s largest gold-producing regions; however, Precambrian-aged gold deposits within the NCC are relatively rare. This study aims to determine the formation age and evolutionary history of the Liyuan gold deposit (5 t Au), which is situated within high-grade metamorphic rocks of the Trans-North China Orogen. We employed U-Pb dating of hydrothermal apatite and rutile, as well as trace element analysis of texturally distinct pyrite. Two distinct stages of gold mineralization were identified. Stage I is characterized by the presence of disseminated pyrite that predominantly associated with lattice-bound gold. In contrast, stage II is marked by quartz-sulfide vein-style mineralization with visible gold and gold microinclusions within pyrite. Pyrite from Stage I (Py1) exhibits elevated As concentrations, whereas pyrite from stage II (Py2 and Py3) is distinguished by high levels of Te and Pb. Hydrothermal apatite intergrown with auriferous Py1 yielded U-Pb ages of 1895 ± 19 Ma and 1836 ± 28 Ma, which correspond to the deformation and metamorphism of the Trans-North China Orogen. The presence of positive Eu anomalies in the hydrothermal apatite suggests that it crystallized from a relatively oxidized fluid. The mechanism for the formation of hydrothermal rutile associated with the vein mineralization of stage II, is attributed to the alteration of biotite. Hydrothermal rutile was dated to 128.0 ± 6.4 Ma, which aligns with the Early Cretaceous granitic magmatism in the region. The Liyuan gold deposit was formed as a result of two distinct hydrothermal events occurring during the Paleoproterozoic and Early Cretaceous periods, respectively. This conclusion is supported by comprehensive field, textural, mineralogical, and geochronological analyses. The recently identified Paleoproterozoic orogenic gold mineralization event, which coincided with orogenic deformation and regional metamorphism during the collision between the Western and Eastern Blocks, presents new prospects for gold exploration in the well-endowed NCC. Furthermore, our study highlights the potential of apatite U-Pb dating as a reliable geochronological tool for investigating Precambrian gold deposits in other regions.</div></div>","PeriodicalId":49674,"journal":{"name":"Precambrian Research","volume":"424 ","pages":"Article 107812"},"PeriodicalIF":3.2000,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Precambrian Research","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S030192682500138X","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"GEOSCIENCES, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Accurate dating of Precambrian gold deposits is challenging due to the lack of suitable mineral chronometers. The North China Craton (NCC) is recognized as one of the world’s largest gold-producing regions; however, Precambrian-aged gold deposits within the NCC are relatively rare. This study aims to determine the formation age and evolutionary history of the Liyuan gold deposit (5 t Au), which is situated within high-grade metamorphic rocks of the Trans-North China Orogen. We employed U-Pb dating of hydrothermal apatite and rutile, as well as trace element analysis of texturally distinct pyrite. Two distinct stages of gold mineralization were identified. Stage I is characterized by the presence of disseminated pyrite that predominantly associated with lattice-bound gold. In contrast, stage II is marked by quartz-sulfide vein-style mineralization with visible gold and gold microinclusions within pyrite. Pyrite from Stage I (Py1) exhibits elevated As concentrations, whereas pyrite from stage II (Py2 and Py3) is distinguished by high levels of Te and Pb. Hydrothermal apatite intergrown with auriferous Py1 yielded U-Pb ages of 1895 ± 19 Ma and 1836 ± 28 Ma, which correspond to the deformation and metamorphism of the Trans-North China Orogen. The presence of positive Eu anomalies in the hydrothermal apatite suggests that it crystallized from a relatively oxidized fluid. The mechanism for the formation of hydrothermal rutile associated with the vein mineralization of stage II, is attributed to the alteration of biotite. Hydrothermal rutile was dated to 128.0 ± 6.4 Ma, which aligns with the Early Cretaceous granitic magmatism in the region. The Liyuan gold deposit was formed as a result of two distinct hydrothermal events occurring during the Paleoproterozoic and Early Cretaceous periods, respectively. This conclusion is supported by comprehensive field, textural, mineralogical, and geochronological analyses. The recently identified Paleoproterozoic orogenic gold mineralization event, which coincided with orogenic deformation and regional metamorphism during the collision between the Western and Eastern Blocks, presents new prospects for gold exploration in the well-endowed NCC. Furthermore, our study highlights the potential of apatite U-Pb dating as a reliable geochronological tool for investigating Precambrian gold deposits in other regions.
期刊介绍:
Precambrian Research publishes studies on all aspects of the early stages of the composition, structure and evolution of the Earth and its planetary neighbours. With a focus on process-oriented and comparative studies, it covers, but is not restricted to, subjects such as:
(1) Chemical, biological, biochemical and cosmochemical evolution; the origin of life; the evolution of the oceans and atmosphere; the early fossil record; palaeobiology;
(2) Geochronology and isotope and elemental geochemistry;
(3) Precambrian mineral deposits;
(4) Geophysical aspects of the early Earth and Precambrian terrains;
(5) Nature, formation and evolution of the Precambrian lithosphere and mantle including magmatic, depositional, metamorphic and tectonic processes.
In addition, the editors particularly welcome integrated process-oriented studies that involve a combination of the above fields and comparative studies that demonstrate the effect of Precambrian evolution on Phanerozoic earth system processes.
Regional and localised studies of Precambrian phenomena are considered appropriate only when the detail and quality allow illustration of a wider process, or when significant gaps in basic knowledge of a particular area can be filled.