Junhui Li , Huizi Liu , Yibo Liu , Bin Wen , Lifeng Zhang , Changzeng Fan
{"title":"Nonamagnesium diruthenium, Mg9Ru2","authors":"Junhui Li , Huizi Liu , Yibo Liu , Bin Wen , Lifeng Zhang , Changzeng Fan","doi":"10.1107/S2414314625003050","DOIUrl":null,"url":null,"abstract":"<div><div>A monoclinic ordered Mg<sub>9</sub>Ru<sub>2</sub> phase with <em>C</em>2<em>/c</em> space-group symmetry rather than previously reported cubic Mg<sub>44</sub>Ru<sub>7</sub> or Mg<sub>3</sub>Ru<sub>2</sub> was obtained <em>via</em> high-pressure sintering during the effort of synthesizing a target Mg—Ru—B compound.</div></div><div><div>A monoclinic phase with chemical composition of Mg<sub>9</sub>Ru<sub>2</sub>, nonamagnesium diruthenium, was obtained through high-pressure sintering of a mixture with an initial chemical composition of MgRuB. The Mg<sub>9</sub>Ru<sub>2</sub> phase crystallizes in the <em>C</em>2<em>/c</em> space group with <em>Z</em> = 8 and is isotypic with the previously reported In<sub>0.74</sub>Ir<sub>3.3</sub>Mg<sub>17.96</sub> and In<sub>1.9</sub>Ir<sub>3</sub>Mg<sub>17.1</sub> phases.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (159KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314625000239","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A monoclinic ordered Mg9Ru2 phase with C2/c space-group symmetry rather than previously reported cubic Mg44Ru7 or Mg3Ru2 was obtained via high-pressure sintering during the effort of synthesizing a target Mg—Ru—B compound.
A monoclinic phase with chemical composition of Mg9Ru2, nonamagnesium diruthenium, was obtained through high-pressure sintering of a mixture with an initial chemical composition of MgRuB. The Mg9Ru2 phase crystallizes in the C2/c space group with Z = 8 and is isotypic with the previously reported In0.74Ir3.3Mg17.96 and In1.9Ir3Mg17.1 phases.