Frederick P. Malan , Kariska Potgieter , Reinout Meijboom
{"title":"(Nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I)","authors":"Frederick P. Malan , Kariska Potgieter , Reinout Meijboom","doi":"10.1107/S2414314625002962","DOIUrl":null,"url":null,"abstract":"<div><div>The significant structural feature in the title Ag<sup>I</sup> complex is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry.</div></div><div><div>The molecular structure of the title Ag<sup>I</sup> complex, [Ag(NO<sub>2</sub>)(C<sub>18</sub>H<sub>12</sub>F<sub>3</sub>P)<sub>2</sub>], features a distorted tetrahedral geometry about the central Ag<sup>I</sup> atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group <em>P</em>2<sub>1</sub>/<em>n</em>, with <em>Z</em> = 4 and <em>Z</em>′ = 1.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (364KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314625000306","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The significant structural feature in the title AgI complex is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry.
The molecular structure of the title AgI complex, [Ag(NO2)(C18H12F3P)2], features a distorted tetrahedral geometry about the central AgI atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group P21/n, with Z = 4 and Z′ = 1.
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