The problematic of soil contamination by industries in a protected area in Portugal.

IF 3.2 3区 环境科学与生态学 Q3 ENGINEERING, ENVIRONMENTAL
Fernando Michels, Joana Ribeiro, Maria Helena Henriques
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Abstract

Understanding the environmental legacy surrounding abandoned industrial sites, once powered by fossil fuels and operated in times of less stringent environmental regulations, is crucial today. This issue is especially pertinent in regions that have since become protected areas. Cabo Mondego, recognized internationally for its geological diversity, designated as a National Monument of Portugal, and included in the Atlantic Geopark project, represents such a region due to its history of potentially degrading activities associated with coal mining and an industrial complex focused on cement and lime production. To ensure the sustainable use of this protected area, it is essential to assess soil health. In this study, fifty soil samples were collected from areas bordering the decommissioned industrial complex and coal mining remnants. The research detected contaminants, their geochemical associations, and potential sources. The evaluation included comparisons with reference values, assessment of the contamination severity, multivariate data analysis, and spatial distribution analysis. Three primary anthropogenic sources of soil contamination were identified: (1) atmospheric emissions from the industrial complex, primarily linked to As and Se contamination, with additional samples showing contamination by Ni, V, and Cr; (2) localized coal mining waste disposal, associated with As, Mo, and Se contamination; and (3) isolated fuel contamination, indicated by elevated Pb levels. Additionally, the study suggests that geogenic sources contribute to the elevated As and U levels in soils with specific geological characteristics. This characterization of potential toxic contaminants in Cabo Mondego enhances the understanding of the region's vulnerabilities and highlights the importance of its protection.

在葡萄牙的一个保护区的工业污染土壤的问题。
如今,了解废弃工业遗址周围的环境遗产至关重要,这些遗址曾经以化石燃料为动力,在环境法规不那么严格的时代运行。这一问题在已成为保护区的地区尤为重要。蒙台哥角(Cabo Mondego)因其地质多样性而受到国际认可,被指定为葡萄牙国家纪念碑,并被列入大西洋地质公园项目。蒙台哥角是这样一个地区的代表,因为它与煤炭开采和水泥和石灰生产相关的潜在退化活动的历史。为了确保这一保护区的可持续利用,必须评估土壤健康状况。在这项研究中,从与退役工业综合体和煤矿遗址接壤的地区收集了50个土壤样本。这项研究检测了污染物,它们的地球化学关联,以及潜在的来源。评价包括与参考值比较、污染严重程度评价、多变量数据分析和空间分布分析。确定了土壤污染的三个主要人为来源:(1)工业园区的大气排放,主要与砷和硒污染有关,其他样品显示Ni, V和Cr污染;(2)与砷、钼、硒污染相关的局部煤矿废弃物处置;(3)分离的燃料污染,表明铅水平升高。此外,研究表明,地质源对具有特定地质特征的土壤中As和U水平的升高有贡献。对蒙台哥角潜在有毒污染物的描述增强了对该地区脆弱性的认识,并强调了保护该地区的重要性。
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来源期刊
Environmental Geochemistry and Health
Environmental Geochemistry and Health 环境科学-工程:环境
CiteScore
8.00
自引率
4.80%
发文量
279
审稿时长
4.2 months
期刊介绍: Environmental Geochemistry and Health publishes original research papers and review papers across the broad field of environmental geochemistry. Environmental geochemistry and health establishes and explains links between the natural or disturbed chemical composition of the earth’s surface and the health of plants, animals and people. Beneficial elements regulate or promote enzymatic and hormonal activity whereas other elements may be toxic. Bedrock geochemistry controls the composition of soil and hence that of water and vegetation. Environmental issues, such as pollution, arising from the extraction and use of mineral resources, are discussed. The effects of contaminants introduced into the earth’s geochemical systems are examined. Geochemical surveys of soil, water and plants show how major and trace elements are distributed geographically. Associated epidemiological studies reveal the possibility of causal links between the natural or disturbed geochemical environment and disease. Experimental research illuminates the nature or consequences of natural or disturbed geochemical processes. The journal particularly welcomes novel research linking environmental geochemistry and health issues on such topics as: heavy metals (including mercury), persistent organic pollutants (POPs), and mixed chemicals emitted through human activities, such as uncontrolled recycling of electronic-waste; waste recycling; surface-atmospheric interaction processes (natural and anthropogenic emissions, vertical transport, deposition, and physical-chemical interaction) of gases and aerosols; phytoremediation/restoration of contaminated sites; food contamination and safety; environmental effects of medicines; effects and toxicity of mixed pollutants; speciation of heavy metals/metalloids; effects of mining; disturbed geochemistry from human behavior, natural or man-made hazards; particle and nanoparticle toxicology; risk and the vulnerability of populations, etc.
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