Christina Yu Jiang , Richard J. Staples , Shannon M. Biros
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引用次数: 0
Abstract
The crystal structure of the title compound features C=O⋯π interactions along with C—H⋯O hydrogen bonds.
In the molecule of 4-({3-[(3,5-dioxo-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-en-4-yl)methyl]phenyl}methyl)-4-azatetracyclo[5.3.2.02,6.08,10]dodec-11-ene-3,5-dione, C30H28N2O4, which contains two substituted [2.2.2]bicyclooctene ring systems linked through a m-xylenediamine ring, the six-membered rings of the bicyclooctene ring systems adopt nearly perfect boat conformations as determined from Cremer–Pople analysis. Both ring systems are fused to a five-membered imide ring that is oriented endo to a bridgehead cyclopropyl ring. The crystal structure features C=O⋯π interactions along with C—H⋯O hydrogen bonds.
期刊介绍:
Acta Crystallographica Section E: Crystallographic Communications is the IUCr''s open-access structural communications journal. It provides a fast, simple and easily accessible publication mechanism for crystal structure determinations of inorganic, metal-organic and organic compounds. The electronic submission, validation, refereeing and publication facilities of the journal ensure rapid and high-quality publication of fully validated structures. The primary article category is Research Communications; these are peer-reviewed articles describing one or more structure determinations with appropriate discussion of the science.