Construction of an organic cage-based porous ionic liquid using an aminal tying strategy.

IF 3.2 3区工程技术 Q2 CHEMISTRY, PHYSICAL

Molecular Systems Design & Engineering Pub Date : 2025-04-02 DOI:10.1039/d5me00004a

Aiting Kai, Austin Mroz, Kim E Jelfs, Andrew I Cooper, Marc A Little, Rebecca L Greenaway

引用次数: 0

Abstract

An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf₂]₆, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO₂ uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

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利用动物捆绑策略构建有机笼型多孔离子液体。

采用动物系结法对柔性有机笼RCC1进行后合成修饰，制备多孔离子液体。所得的PIL [RCC1-IM][NTf2]6在100°C以下表现出熔融行为，在熔体淬火、二氧化碳吸收时向玻璃相转变，并且通过分子动力学模拟证实了其永久孔隙率。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Molecular Systems Design & Engineering Engineering-Biomedical Engineering

CiteScore

6.40

自引率

2.80%

发文量

144

期刊介绍： Molecular Systems Design & Engineering provides a hub for cutting-edge research into how understanding of molecular properties, behaviour and interactions can be used to design and assemble better materials, systems, and processes to achieve specific functions. These may have applications of technological significance and help address global challenges.