Temperature-Regulated Wettability of Conductive Films Based on Electrophoretic Silver Nanoparticle Concentrates

IF 1.4 4区 化学 Q4 CHEMISTRY, PHYSICAL
S. I. Babashova, V. V. Bocharov, V. S. Sulyaeva, E. A. Maksimovskiy, A. N. Kolodin, A. I. Bulavchenko
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引用次数: 0

Abstract

Uniform rough films containing up to 73 at % silver have been obtained by the Doctor Blade method from concentrated silver nanoparticle organosols stabilized with sodium bis(2-ethylhexyl) sulfosuccinate. Variations in the wettability of the films have been studied in detail as depending on the conditions of their heat treatment within a temperature range of 50–500°C. The temperature dependence of the contact angles is not monotonic and implies the transition from superhydrophilic to weakly hydrophilic systems due to the processes of sintering of nanoparticles and thermal decomposition of the stabilizer. It has been experimentally shown that a transition from nonconductive to conductive coatings (from 500 to 105 mΩ/sq) is accompanied by a drastic increase in the contact angle (from 25 to 78°).

基于电泳纳米银精矿的导电膜的温控润湿性
用双(2-乙基己基)磺基琥珀酸钠稳定的浓缩银纳米颗粒有机溶胶,用Blade博士方法获得了银含量高达73%的均匀粗糙薄膜。在50-500°C的温度范围内,薄膜的润湿性的变化已经被详细研究,这取决于它们的热处理条件。接触角的温度依赖性不是单调的,这意味着纳米颗粒的烧结和稳定剂的热分解过程导致了从超亲水性到弱亲水性的转变。实验表明,从不导电到导电涂层的转变(从500到105 mΩ/sq)伴随着接触角的急剧增加(从25到78°)。
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来源期刊
Colloid Journal
Colloid Journal 化学-物理化学
CiteScore
2.20
自引率
18.20%
发文量
36
审稿时长
6-12 weeks
期刊介绍: Colloid Journal (Kolloidnyi Zhurnal) is the only journal in Russia that publishes the results of research in the area of chemical science dealing with the disperse state of matter and surface phenomena in disperse systems. The journal covers experimental and theoretical works on a great variety of colloid and surface phenomena: the structure and properties of interfaces; adsorption phenomena and structure of adsorption layers of surfactants; capillary phenomena; wetting films; wetting and spreading; and detergency. The formation of colloid systems, their molecular-kinetic and optical properties, surface forces, interaction of colloidal particles, stabilization, and criteria of stability loss of different disperse systems (lyosols and aerosols, suspensions, emulsions, foams, and micellar systems) are also topics of the journal. Colloid Journal also includes the phenomena of electro- and diffusiophoresis, electro- and thermoosmosis, and capillary and reverse osmosis, i.e., phenomena dealing with the existence of diffusion layers of molecules and ions in the vicinity of the interface.
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