Lightweight SiCN ceramics doped with rare earth elements for electromagnetic wave absorption and infrared stealth

IF 5.8 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS
Chang Liu , Kaidi Mao , Hang Teng , Rui Zhang , Haibin Sun , Qiangqiang Hu , Cuncheng Li , Hongyu Gong , Paolo Colombo , Xue Guo , Yurun Feng
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Abstract

This study demonstrates the electromagnetic simulation-guided additive manufacturing of SiCN ceramics with a gyroid architecture for enhanced microwave absorption. Rare earth (Ce, Pr) doping enables the precipitation of polarization-active SiC/C phases after low-temperature pyrolysis (900°C), synergistically optimizing impedance matching and electromagnetic energy dissipation. The optimized ceramics exhibit exceptional performance: GS-Ce900 achieves full X-band coverage at 3.86–4.07 mm thickness, while GS-Pr900 delivers a minimum reflection loss of −30.99 dB at 2.73 mm. Furthermore, under 60 s of electromagnetic irradiation, GS-Pr900 demonstrates an 84.3°C temperature decrease via thermoelectric conversion, showcasing strong infrared stealth potential.
用于电磁波吸收和红外隐身的稀土轻量化SiCN陶瓷
本研究演示了电磁模拟引导下的用于增强微波吸收的具有陀螺结构的SiCN陶瓷的增材制造。稀土(Ce, Pr)掺杂使900℃低温热解后析出极化活性SiC/C相,协同优化阻抗匹配和电磁能量耗散。优化后的陶瓷表现出优异的性能:GS-Ce900在3.86-4.07 mm厚度范围内实现了全x波段覆盖,而GS-Pr900在2.73 mm厚度范围内的反射损耗最小为- 30.99 dB。此外,在60 s的电磁辐照下,GS-Pr900通过热电转换显示出84.3°C的温度下降,显示出强大的红外隐身潜力。
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来源期刊
Journal of The European Ceramic Society
Journal of The European Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
10.70
自引率
12.30%
发文量
863
审稿时长
35 days
期刊介绍: The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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